Fluorinated aldehyde containing polymers

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From aldehyde or derivative thereof as reactant

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568490, 568448, 568449, 568495, 528230, 528232, 528233, 528238, C08G 1002

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active

055126529

ABSTRACT:
Fluorinated aldehydes are made by reacting a fluorinated acyl chloride with a silicon hydride in the presence of palladium. Also disclosed are fluorinated ether aldehydes and their polymers, a process for making fluorinated aldehydes polymers using titanium or aluminum alkoxide catalysts, and a process for endcapping fluorinated polymers using perfluoroallyl fluorosulfate or fluorine.

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J. D. Citron, J. Org. Chem., 34, 1977-1979, 1969.
J. D. Citron, J. Org. Chem., 36, 2547-2548, 1971.
K. Neeld et al., J. Polym. Sci. Macromol Rev., 16, 1-40, 1981.

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