Fluorescent material, process for producing the same and...

Compositions – Inorganic luminescent compositions – Compositions containing halogen; e.g. – halides and oxyhalides

Reexamination Certificate

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C313S486000

Reexamination Certificate

active

08080174

ABSTRACT:
A fluorescent material comprising: a β-Sialon expressed by the general formula Si6-ZAlZOZN8-Zas a host material; and Eu dissolved in solid solution as a luminescence center, is a powder which, when measured by the laser diffraction scattering method, gives particle diameter distribution in which cumulative 10% diameter (D10) falls within the 7 μm to 20 μm range and 90% diameter (D90) within the 50 μm to 90 μm range, and can be used as a fluorescent material low in luminescence intensity degradation ideal for illuminators. This fluorescent material can be produced by subjecting a raw powder, which is obtained by mixing a silicon nitride powder, aluminum nitride powder, and aluminum-containing or Eu-containing compound as required, to heating at 1850° C. to 2050° C. for 9 hours or longer in a nitrogen or nonoxidizing atmosphere.

REFERENCES:
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Translation of PCT/ISA/237, IB338, and IB373 of PCT/JP2007/061529.
J. W. H. Van Krebel, “On new rare earth doped M-Si—Al—O—N materials,” Tu Eindhoven, The Netherlands, pp. 145-161 (1998).
Extended Abstracts of the 65th Meeting, Japan Society of Applied Physics, (Sep. 2004, Tohoku Gakuin University), No. 3, pp. 1282-1284.
Extended Abstracts of the 52nd Meeting, Japan Society of Applied Physics and Related Societies, (Mar. 2005, Saitama University) No. 3, p. 1615.
Naoto Hirosaki et al., “Characterization and properties of green-emitting β-SiALON:Eu2+ powder phosphors for white light-emitting diodes”, Applied Physics Letters, vol. 86, No. 21, pp. 211905.1-211905.3, (2005).
International Search Report (ISR) for PCT/JP2007/061529.
PCT/ISA/237 in PCT/JP2007/061529 and its English translation of Section V.

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