Fluorene compounds and methods for making

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

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556 95, 556400, 556465, 556466, 556478, C07F 702, C07F 722, C07F 730

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active

053470265

ABSTRACT:
A Process is disclosed comprising reacting an alkali metal salt of Z with MX.sub.4 to form a trihalo compound; reacting the trihalo compound with an alkali metal salt of Z' to form a dihalo compound; and reacting the dihalo compound with at least one alkali metal organic compound to form Z-MR.sub.2 -Z', where Z is a substituted or unsubstituted fluorenyl radical, M is Ge, Si, or Sn, X is Cl, Br, F, or I, each R is a hydrocarbyl radical containing 1 to 20 carbon atoms, and Z' is an unsubstituted cyclopentadienyl, substituted cyclopentadienyl, unsubstituted indenyl, substituted indenyl, unsubstituted fluorenyl, or a substituted fluorenyl. Also new fluorene compounds are disclosed.

REFERENCES:
patent: 5191132 (1993-03-01), Patsidis et al.
patent: 5210352 (1993-05-01), Alt et al.
Manipulation of Organoactinide Coordinative Unsaturation. Synthesis, Structures and Reactivity of Thorium Hydrocarbyls and Hydrides with Chelating Bis(tetramethylcyclopentadienyl) Ancillary Ligands, Organometallics 1988, 7, pp. 1828-1838 Application 734,853, filed Jul. 23, 1991, S. Palackal et al.

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