Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing
Patent
1993-06-11
1994-09-13
Dees, Jose' G.
Organic compounds -- part of the class 532-570 series
Organic compounds
Heavy metal containing
556 95, 556400, 556465, 556466, 556478, C07F 702, C07F 722, C07F 730
Patent
active
053470265
ABSTRACT:
A Process is disclosed comprising reacting an alkali metal salt of Z with MX.sub.4 to form a trihalo compound; reacting the trihalo compound with an alkali metal salt of Z' to form a dihalo compound; and reacting the dihalo compound with at least one alkali metal organic compound to form Z-MR.sub.2 -Z', where Z is a substituted or unsubstituted fluorenyl radical, M is Ge, Si, or Sn, X is Cl, Br, F, or I, each R is a hydrocarbyl radical containing 1 to 20 carbon atoms, and Z' is an unsubstituted cyclopentadienyl, substituted cyclopentadienyl, unsubstituted indenyl, substituted indenyl, unsubstituted fluorenyl, or a substituted fluorenyl. Also new fluorene compounds are disclosed.
REFERENCES:
patent: 5191132 (1993-03-01), Patsidis et al.
patent: 5210352 (1993-05-01), Alt et al.
Manipulation of Organoactinide Coordinative Unsaturation. Synthesis, Structures and Reactivity of Thorium Hydrocarbyls and Hydrides with Chelating Bis(tetramethylcyclopentadienyl) Ancillary Ligands, Organometallics 1988, 7, pp. 1828-1838 Application 734,853, filed Jul. 23, 1991, S. Palackal et al.
Alt H. G.
Palackal Syriac J.
Patsidis Konstantinos
Dees Jos,e G.
Michel Marianne H.
Nazario-Gonzalez Porfirio
Phillips Petroleum Company
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