Fluorene compounds

Details Fluorene compounds Fluorene compounds

1986-09-22

2002-05-28

Hess, Bruce H. (Department: 1774)

Record receiver having plural interactive leaves or a colorless

Having a colorless color-former, developer therefor, or...

Identified color-former

C427S151000, C549S265000

Reexamination Certificate

active

06395681

ABSTRACT:

This invention relates to novel fluorene compounds, a process for their manufacture and recording materials comprising same.
More particularly, this invention pertains to novel chromogenic compounds which can give intense colors when they are contacted with an electron accepting co-reactant. Even more specifically, this invention relates to chromogenic compounds eligible for use in pressure-sensitive or heat-sensitive mark-forming record systems. Such systems are improved by use of these compounds. As used in mark-forming systems, marking in desired areas on support webs or sheets may be accomplished by effecting localized reactive contact between the chromogenic material and the electron accepting material on or in such a web or sheet, such material being brought thereto by transfer, or originally there in situ, the desired reactive contact forming colored images in the intended image-marking areas.
The chromogenic compounds of this invention have the following general formula:
wherein E represents a six-membered aromatic or heterocyclic ring which may have an aromatic condensed ring and both the E ring and the condensed ring may be substituted.
Each of R
1
, R
2
, R
3
and R4 independently represents hydrogen, alkyl of not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy or represents cycloalkyl, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl or lower alkoxy or R
1
and R
2
or R
3
and R
4
together with the nitrogen atom to which they are attached represent a 5- or 6-membered heterocyclic radical.
Each of R
7
and R
8
independently represents hydrogen, lower alkyl, lower alkoxy or halo.
In the above definition of the radicals, lower alkyl or lower alkoxy denotes, as a rule, those groups which contain 1 to 5, preferably 1 to 3, carbon atoms.
Alkyl groups represented by R
1
, R
2
, R
3
, R
4
, R
7
or R
8
can be straight chain or branched. Cycloalkyl is, for example, cyclopentyl or preferably cyclohexyl.
If R
1
and R
2
or R
3
and R
4
, together with the nitrogen atom to which they are attached, represent a heterocyclic radical, such a radical is, for example, pyrrolidino, piperidino, pipecolino, morpholino, thiomorpholino or piperazino.
U.S. Pat. Nos. 4,020,056; 4,022,771; 4,026,883; 4,107,428; and 4,119,776 disclose compounds having near infrared absorption and chromogenic properties. U.S. Pat. Nos. 3,344,189 and 3,413,071 and German Patent No. 2,145,027 disclose fluorene dye derivatives.
Of recording materials using colorless chromogenic compounds there are known a variety of forms such as pressure-sensitive copying paper, heat-sensitive recording paper, electrothermal recording paper, or the like, and with the advent of an informationalized era there is an increasing demand for these recording materials. Moreover, in recent years, computers have come into wide use for the rationalization of business, so that optical character readers are in use for feeding information to computers. Such an optical character reader is a device which can read information by the aid of the wavelengths in the near infrared region. Accordingly, in order to read information by means of an optical character reader it is essential that the information should be recorded with some material which is capable of absorbing the wavelengths in the near infrared region. However, the image obtained with the recording materials using the conventional chromogenic compounds had no absorption in the near infrared region, so that they had a shortcoming of being illegible by means of an optical character reader.
It has been discovered that recording materials comprising the fluorene compounds of this invention as the chromogenic material show remarkably good combination of color forming capability and absorption in the near infrared region.
An important use for the compounds of this invention resides in their incorporation into pressure- or heat-sensitive record systems as a colorable reactant for development of color on application of a mark-forming force. Hence, it is an object of this invention to provide substances having near infrared color response and chromogenic properties, which substances can be incorporated in a web or coated onto the surface of a web to provide a record sheet or a manifolding unit, and which are useful in carrying out methods of marking involving a reactive contact with a color-activating material to develop dark-colored materials in areas where marking is desired.
It is an object of this invention to provide improved compounds, based upon the aforementioned fluorene compounds, which are substantially colorless, or slightly colored, offering a variety of chromogenic characteristics, and developing dark-colored substances absorbing at visible and infrared wavelengths upon contact with color-activating materials.
The fluroene compounds of this invention represented by the general formula (1) are novel and in themselves substantially colorless crystals showing no absorption in the near infrared region, but when in contact with color-developing agents such as, for example, Japanese acid clay, phenol-formaldehyde polymers, hydroxybenzoic acid, bisphenol A, etc. they form a blue to green color, and the resulting color-formed image shows not only marked absorption in the near infrared region but also excellent light fastness. Thus, the fluorene compounds of this invention represented by the general formula (1) are possessed of excellent properties as the chromogenic material.
Compounds of this invention having an interesting utility are those of the formula:
wherein
E is:
R
9
, R
10
, R
11
and R
12
are: hydrogen, halogen or
each of R
1
, R
2
, R
3
, R
4
, R
5
and R
6
is independently hydrogen, alkyl of not more than 12 carbon atoms which is unsubstituted or substituted by halogen, hydroxyl, cyano or lower alkoxy or is cycloalkyl, phenyl, benzyl, or phenyl or benzyl which is substituted by halogen, lower alkyl or lower alkoxy or R
1
and R
2
or R
3
and R
4
or R
5
and R
6
together with the nitrogen atom to which they are attached is a 5- or 6-membered heterocyclic radical selected from the group consisting of pyrrolidino, piperidino; pipecolino, morpholino, thiomorpholino and piperazino; and
each of R
7
and R
8
is independently hydrogen, lower alkyl, lower alkoxy or halo.
Particularly interesting fluorene compounds of this invention are those of the formula:
wherein E represents an optionally substituted benzene, naphthalene, pyridine or pyrazine ring.
Each of R
1
, R
2
, R
3
and R
4
independently represents hydrogen, alkyl of not more than 12 carbon atoms, cyclohexyl, phenyl, benzyl or tolyl or R
1
and R
2
or R
3
and R
4
together with the nitrogen atom to which they are attached represent pyrrolidino, piperidino, pipecolino, morpholino, thiomorpholino or piperazino.
R
7
and R
8
are as previously defined.
The preferred fluorene compounds of this invention are those of the formula:
wherein each of R
1
, R
2
, R
3
, R
4
, R
5
and R
6
independently represents hydrogen, alkyl of not more than 12 carbon atoms, cyclohexyl, phenyl, benzyl or tolyl or R
1
and R
2
or R
3
and R
4
or R
5
and R
6
together with the nitrogen atom to which they are attached represent pyrrolidino, piperidino, pipecolino, morpholino, thiomorpholino or piperazino.
Especially preferred fluorene compounds of the formula (4) are those wherein each of R
1
, R
2
, R
3
, R
4
, R
5
and R
6
independently represents alkyl of not more than four carbon atoms.
This invention also relates to a process for the manufacture of the fluorene compounds represented by formulas (1), (2), (3) and (4) which comprises subjecting the compound represented by the following general formula to diazotization followed by ring closure:
wherein E, R
1
, R
2
, R
3
, R
4
, R
7
, and R
8
are as previously defined.
The chromogenic compounds of this invention are eligible for use in pressure-sensitive and thermally-sensitive mark-forming systems. Pressure-sensitive mark-forming systems provide a marking system of disposing on and

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