Fluidized bed process for producing acrylonitrile and catalytic

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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502240, 502242, 502246, 502249, C07C12014

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active

045459436

ABSTRACT:
Acrylonitrile is produced by passing a gaseous mixture comprising propylene, molecular oxygen and ammonia upwardly through a fluidized bed comprising particles of a highly-active acrylonitrile catalyst in physical admixture with particles of a composite consisting essentially of antimony oxide and silica. The use of the antimony oxide-silica composite moderates the effect of the highly-active acrylonitrile catalyst reducing its activity sufficiently to enable the use of longer residence times, but without reducing the acrylonitrile selectivity of the catalyst.

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