Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Processes of preparing a desired or intentional composition...
Reexamination Certificate
2000-06-02
2003-01-14
Cain, Edward J. (Department: 1714)
Synthetic resins or natural rubbers -- part of the class 520 ser
Synthetic resins
Processes of preparing a desired or intentional composition...
Reexamination Certificate
active
06506817
ABSTRACT:
FIELD OF THE INVENTION
This invention relates to the foundry field, more specifically to a new lustrous carbon former.
BACKGROUND
Lustrous carbon formers are carbon-containing substances added to casting sand in foundries to facilitate release, at the moment of casting, hydrocarbon type volatile materials. The role of such carbon formers is to create a reducing atmosphere in the mold enclosure, and to form a carbon deposit of graphitic appearance on the surface of the castings, thereby improving their appearance.
Traditionally, finely ground coal dust is the most widely used substance, with a lustrous carbon formation capacity on the order of 8 to 10% of its weight. Other substances, such as tars, bitumens, certain resins, or polymers such as polystyrene, are used in mixture with the coal dust so as to increase the lustrous carbon formation capacity.
Most of the lustrous carbon formers are used in the form of a finely divided powder the grain size of which is smaller than 650 microns, with more than 50% smaller than 150 microns. However, these powders, which are organic in nature, are susceptible of spontaneous combustion, dust explosion and clumping in their containment silos.
Certain manufacturers, including the Applicant, have attempted to replace the powders with liquids such as bituminous oils to overcome these drawbacks. It has been found in practice that these oils could not be incorporated in the sand in a sufficient quantity to satisfy the lustrous carbon requirement because the sand becomes too plastic and there is an excessive emission of fumes upon casting. The use of these oils has, therefore, remained limited to a few special cases. Other manufacturers have tried to commercialize suspensions of coal dust in water, but this product has been found to be too expensive compared to conventional coal dust.
Certain manufacturers have somewhat circumvented the problem of storing pulverulent materials by mixing them with bentonite, which is another common component of foundry casting sand. These mixtures, which have acquired a notable share of the market in Europe, exhibit a lustrous carbon formers/bentonite ratio between 5 and 0.2. However, the favorable influence of such mixtures on the storage safety problems is only perceptible for high bentonite contents and the safety problems are not truly resolved. In addition, these mixtures are less flexible for foundry use because the lustrous carbon formers/bentonite ratio is predefined. This often forces the foundries to maintain a small separate stock of lustrous carbon formers.
The toxicity problems of the polycyclic aromatic hydrocarbons generated by the lustrous carbon formers such as coal justify the search for new replacement or enrichment products, the selection of which is still limited by the demanding criteria concerning the storage of pulverulent material.
SUMMARY OF THE INVENTION
The invention provides a solution to the problems outlined above. This is attained in one aspect of the invention by means of an additive for foundry casting sands enabling formation of lustrous carbon and consisting of a fluid composition comprising a liquid support and particles of at least one substance other than coal which is capable of forming lustrous carbon during metal casting.
In another aspect, the invention includes a process for the preparation of a composition for foundry molding comprising mixing foundry sand with at least about 0.05% by weight of the additive either directly or as an intermediary of a premix with other materials.
DETAILED DESCRIPTION OF THE INVENTION
It will be appreciated that the following description is intended to refer to specific embodiments of the invention selected for illustration in the following text and is not intended to define or limit the invention other than in the appended claims.
Advantageously, the content of liquid support in the fluid composition of the invention is less than about 60% by weight of the composition. The liquid support is preferably water but it can also be selected from among the organic liquids stemming from the distillation of petroleum or coal, liquid derivatives extracted from plants and the like. The following can be cited as preferred examples: aromatic solvents, fatty acids, naphthene or terpene derivatives as well as their mixtures, alone or in water. In the compositions of the invention in which the liquid support is a mixture of water and at least one organic liquid, the water represents advantageously at least about 30% of the weight of the liquid support and/or at least about 5% by weight of the fluid composition of the invention.
The term “fluid composition” is understood to mean liquids as well as suspensions or pastes, which are essentially homogenous at least during their use.
The content of particles of a substance other than coal which is capable of forming lustrous carbon in the fluid composition of the invention is between about 85 and 5% by weight of the composition. Preferably, at least about 50% by weight of the particles in the composition of the invention are of a size smaller than about 500 microns.
All substance particles known for their capability to form lustrous carbon during metal casting in the mold use in the prior art in pulverulent form can be used within the framework of the invention. Especially preferred are bitumens, gilsonite, coumarone-indene resins, albores, certain polyolefins or polymers derived from them, resinous compounds obtained by the treatment of bis-phenol A manufacturing residues and the like.
However, the particles can also be constituted of any other material which is potentially beneficial but has drawbacks for application in pulverulent form, especially because of unfavorable physical characteristics such as, for example, poor suitability for grinding, high moisture content, tendency to clumping or to granular segregation. These materials are often waste products from polymer production, which are, at present, most frequently incinerated. The following are preferred examples of such materials: residues from the manufacture in emulsion or in suspension of polyolefins or their copolymers, residues which are often constituted of slurries or wet fines, residues from the granulometric selection of ion-exchange resins and the like.
Thus, in a general manner, the invention pertains to the use within a liquid support of particles of resinous compositions and, more specifically, of particles of polymer or copolymer or their mixture, the macromolecular chains of which comprise carbon and hydrogen atoms to the extent of at least about 80% of their weight. Among these, the invention envisages preferentially those of which:
The lustrous carbon formation capacity is at least about 15% by weight of their weight, measured by the method defined by the German foundry industry in Bestimmung von Glanzkohlenstoff—V.D.G. p. 85, October 1980.
The volatile material content is at least about 50% measured according to the ISO method 562-1981 and at least about 80% of the volatile material is released between about 200° C. and about 500° C.
The particles of substances capable of forming lustrous carbon which are preferred according to the invention have a low content of polycyclic aromatic hydrocarbons (e.g., benzo[a]pyrene <about 50 ppm) and a sulfur content lower than about 3%.
The fluid composition according to the invention can also comprise an adequate amount of one or more antisettling agents, flow agents or surface-active agents to prevent decantation of the particles or separation of the liquid phases. The following are among the preferred agents: clays, bentonites, surface-active agents, polysaccharides and the like.
The fluid composition of the invention can also include one or more additives known for their favorable effects in foundry sand, for example, of improving its fluidity, cohesion or locking. These additives can be, for example, saponified oils, fatty acids or their saponified or unsaponified esters, glycols, graphite, additives acting on bentonite activation such as certain bases and the like.
The fluid co
Huttenes-Albertus France (S.A.R.L.)
Lee Katarzyna W.
Schnader Harrison Segal & Lewis LLP
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