Fluid bed process for the acetoxylation of ethylene in the...

Organic compounds -- part of the class 532-570 series – Organic compounds – Carboxylic acid esters

Reexamination Certificate

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Reexamination Certificate

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10721669

ABSTRACT:
A fluid bed process for the manufacture of vinyl acetate from ethylene, acetic acid and oxygen comprising feeding ethylene and acetic acid into a fluid bed reactor through a first inlet, introducing the oxygen into the reactor through a second inlet, co-joining the oxygen, ethylene and acetic acid in the reactor in contact with a fluid bed catalyst to produce vinyl acetate. The particle size diameter of the particulate catalyst material has a range of 60% of the particles being below 200 microns (0.1 mm) with no more than 40% of the particles being below 40 microns (0.04 mm).

REFERENCES:
patent: 3714237 (1973-01-01), Calcagno
patent: 5550281 (1996-08-01), Cirjak et al.
patent: 5688993 (1997-11-01), Provine
patent: 5710318 (1998-01-01), Cirjak et al.
patent: 1266623 (1972-01-01), None
patent: 1266624 (1972-01-01), None
patent: 1266623 (1972-03-01), None
patent: 1266624 (1972-03-01), None

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