Flue gas desulfurization process

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Sulfur or sulfur containing component

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423242, C01B 1700, B01D 800

Patent

active

050342045

ABSTRACT:
A wet, calcium-based, flue gas desulfurization process for reliably and cost effectively removing sulfur dioxide from the flue gas generated by the combustion of fossil flues containing sulfur includes the step of contacting the combustion flue gas preferably as a part of the scrubbing liquor, with an aqueous solution containing formate ions and a dissolved calcium concentration reduction agent. The latter reduces the dissolved calcium concentration present in the flue gas which, in turn reduces the coprecipitation and loss of formate within and from the system. Also, by contacting the flue gas with an aqueous solution comprising formate and thiosulfate ions, the formate coprecipitation within the system is reduced independent of the calcium concentration level within the system.

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