Chemistry: electrical and wave energy – Apparatus – Electrolytic
Patent
1985-09-13
1987-03-24
Andrews, R. L.
Chemistry: electrical and wave energy
Apparatus
Electrolytic
204263, 204284, 204291, 204292, 204294, 204275, 429225, 429228, 4283073, 4283128, 4283184, 4283191, C25B 900
Patent
active
046523553
ABSTRACT:
A flow-through electrochemical cell for sequentially oxidizing and reducing an aryl compound. The cell includes a cell body forming a compartment to hold an aqueous electrolyte solution, a porous anodic electrode, and a porous cathodic electrode. The anodic electrode includes a first porous layer of a hydrophobic material, a second porous layer with an oxidation catalyst dispersed therein, and a current collector in electrical contact with the second layer. The cathodic electrode comprises a block of a porous, electrically-conductive material impregnated with lead particles. The cell is particularly useful for the preparation of aryl hydroquinones at very high current efficiencies, high current densities, and low voltages.
REFERENCES:
patent: 4188268 (1980-02-01), Sugahara et al.
patent: 4302321 (1981-11-01), De Nora et al.
patent: 4387142 (1983-06-01), Lindholm et al.
Andrews R. L.
Howard Dan R.
The Dow Chemical Company
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