Stock material or miscellaneous articles – Composite – Of metal
Patent
1992-12-16
1994-12-13
Nakarani, D. S.
Stock material or miscellaneous articles
Composite
Of metal
4284735, 525426, 15624411, B32B 1508
Patent
active
053728912
ABSTRACT:
An improved polyimide-based coating composition comprising a polyimide upper layer and a polyimide-modified bismaleimide lower layer for use as a coating on metal substrate, such as an electrolytic copper foil. The polyimide are prepared from reactions between diamines, such as p-phenylene diamine and 4-4'-diaminodiphenyl ether, and dianhydrides, such as 3,3',4,4'-benzophenone tetracarboxylic dianhydride and biphenyl-3,3',4,4'-tetracarboxylic dianhydride. The modified bismaleimide can be prepared from reacting an N,N',4,4'-diphenyl bismaleimide with a barbituric acid or its derivative. A double-layered extrusion coating technique having a double-layered extrusion die is utilized to apply the coating composition onto the metal substrate. The final laminated products show improved peel strength between the polyimide coating and the substrate, as well as improved dimensional stability and surface flatness thereof.
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Jpn. Kokai Tokyo Koho JP03/123,093, 61131d (CA Selects, Polyimides, Issue 5, 1992).
T. Paskal, et al., "New Semi-Interpenetrating Polymeric Networks from Linear Polyimides and Thermosetting Bismaleimides:2 Mechanical and Thermal Prop. of the blends," Polymer, 1990, vol. 31, Jan. pp. 78-83.
Chen Han-Lung
King Jinn-Shing
Pan Jing-Pin
Wang Tsung-Hsiung
Yu Tsai-An
Industrial Technology Research Institute
Liauh W. Wayne
Nakarani D. S.
Sand Stephen
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