Flexible aminoplast-curable film-forming compositions and compos

Stock material or miscellaneous articles – Composite – Of polyamidoester

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4284237, 4284242, 428480, 428482, 428483, 428500, 428515, 428524, 524512, 524539, 524541, 525131, 525154, 525157, 525163, 525406, C08L 3314, C08L 6702, C08L 7504

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active

059767014

ABSTRACT:
A flexible, aminoplast-curable film-forming composition can serve as a transparent coating composition for a multi-component composite coating composition having the transparent coating on a pigmented or colored base coat. The film-forming composition comprises at least two polymeric components. One is a polyether polymer containing a plurality of terminal and/or pendant carbamate groups of the structure: ##STR1## Another is at least one additional carbamate functional polymer along with urethane oligomer or is a polyurethane polyol. The former include carbamate functional polyester, acrylic polymer, and polyurethane, where each contains a plurality of terminal and/or pendant carbamate groups of the Structure I depicted above. Also the urethane oligomers has a plurality of carbamate groups of Structure I that are pendant and/or terminal. The latter polyurethane polyol has a plurality of pendant and/or terminal hydroxyl groups and optionally can be used with the urethane polyol and/or any of the aforementioned carbamate functional polymers. Optionally an additional polymer that is present is an acrylic polymer containing a plurality of amide groups with or without a plurality of terminal and/or pendant carbamate groups of Structure I. Also with the presence of the amide functional acrylic polymer, silica can be employed. Additionally for crosslinking the film-forming composition contains an aminoplast crosslinking agent.

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