Flash-spinning of polymeric plexifilaments

Plastic and nonmetallic article shaping or treating: processes – Formation of solid particulate material directly from molten... – By extrusion spraying or gravity fall through orifice

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264205, 264211, 26421114, D01D 511

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active

050323261

ABSTRACT:
An improved process for flash-spinning plexifilamentary film-fibril strands is provided. A 5 to 30 and preferably 10 to 20 percent solution of polymer, preferably linear polyethylene, is formed in a spin fluid that consists essentially of 50 to 90 weight percent methylene chloride and 10 to 50 percent of a halocarbon, which preferably is chlorodifluoromethane, 1,1,1,2-tetrafluoroethane, 1,1-difluoroethane, 1,1,1,2-tetrafluoro-2-chloroethane or 1,1-difluoro-1-chloroethane. The solution is then flash-spun to form high quality plexifilamentary strands. The process avoids the use of halocarbon solvents that could be ozone-depletion hazards.

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P. S. Zurer, "Search Intensifies for Alternatives to Ozone-Depleting Hydrocarbons", Chemical & Engineering News, pp. 17-20 (Feb. 8, 1988).
Fluorocarbon/Ozone Update, "Alternatives to Fully Halogenated Chlorofluorocarbons", The du Pont Development Program, du Pont Bulletin E-90566 (Mar. 1987).

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