Flame-retardant, high temperature resistant polyimide fibers and

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528125, 528126, 528128, 528172, 528173, 528176, 528183, 528188, 528220, 528224, 528229, 528350, 428359, 428364, 428369, 428397, 264168, 26417713, 26417717, 264205, 26421115, 26421117, 264233, 26433116, C08G 7310, D01F 600

Patent

active

053843908

ABSTRACT:
There are disclosed flame-retardant, high temperature resistant polyimide fibers of the general formula ##STR1## wherein n is an integer larger than 1, A is a tetravalent aromatic group and R is at least one divalent aromatic group. These polyimide fibers have been heat-treated in the unstretched state and have a maximum shrinkage of 14% when heated to a temperature of 400.degree. C. These polyimide fibers are produced by initially spinning crude fibers from a solution of the appropriate polyimide in an aprotic organic solvent, preferably according to the dry-spinning method, which solution optionally contains additives. The crude fibers obtained are washed with water to remove the solvent. The washed crude fibers are dried to a moisture content of less than 5% by mass, are subjected to a heat treatment at a temperature of between 315.degree. C and 450.degree. C, are cooled and, if desired, are crimped and cut to staple fibers. What is essential is that the heated crude fibers are heat-treated and cooled in the unstretched state.

REFERENCES:
patent: 3985934 (1976-10-01), Farrissey, Jr. et al.
patent: 4238538 (1980-12-01), Manwiller
patent: 4801502 (1989-01-01), Weinrotter et al.
patent: 5120814 (1992-06-01), Seidl

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