Fixed-bed hydrogen peroxide catalyst

Chemistry of inorganic compounds – Oxygen or compound thereof – Peroxide

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C01B 1502

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active

048000752

ABSTRACT:
An improved fixed-bed cyclic anthraquinone process for production of hydrogen peroxide wherein the improvement is using a hydrogenation catalyst comprising palladium or a mixture of palladium and platinum on a support containing alpha alumina. The preferred range of palladium is 0.1 to 3 weight percent and the preferred range of platinum, when present, is greater than 0.01 weight percent (based on the total weight of the catalyst). The preferred catalyst support contains greater than 5 percent alpha alumina.

REFERENCES:
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patent: 3009782 (1961-11-01), Porter
patent: 3488150 (1970-01-01), Kabisch et al.
patent: 3615207 (1971-10-01), Lee
patent: 3635841 (1972-01-01), Keith et al.
patent: 3887490 (1975-06-01), Schreyer et al.
"Oxides and Hydroxides of Aluminum", Technical Paper No. 19, Alcoa Research Laboratories, (1972).
"Adsorption of Gases in Multimolecular Layers", Journal of the American Chemical Society, vol. 60, pp. 309-321, (2/1938).

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