Fischer-tropsch process

Chemistry: fischer-tropsch processes; or purification or recover – Liquid phase fischer-tropsch reaction

Reexamination Certificate

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Details

C518S705000, C518S715000, C585S315000

Reexamination Certificate

active

07012102

ABSTRACT:
The present invention provides a process for the conversion of synthesis gas to hydrocarbons comprising the steps of: a) contacting synthesis gas at an elevated temperature and pressure with a particulate Fischer-Tropsch catalyst in a Fischer-Tropsch reactor system to generate hydrocarbons comprising gaseous and liquid hydrocarbons; b) in a gas separation zone, separating a gaseous phase comprising saturated gaseous hydrocarbons from a liquid phase comprising liquid hydrocarbons and from the particulate Fischer-Tropsch catalyst; c) passing at least a portion of the separated gaseous phase to a dehydrogenation reactor where at least a portion of the saturated gaseous hydrocarbons are converted to unsaturated hydrocarbons; and d) recycling at least a portion of said unsaturated hydrocarbons back to the Fischer-Tropsch reactor system.

REFERENCES:
patent: 4754092 (1988-06-01), Iglesia et al.
patent: 5939350 (1999-08-01), Singleton et al.
patent: 5961933 (1999-10-01), Casanave et al.
patent: 0 261 870 (1988-03-01), None
patent: 0 522 666 (1993-01-01), None
patent: 2 037 316 (1980-07-01), None
patent: WO 93 15835 (1993-08-01), None
patent: WO 01/38269 (2001-05-01), None

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