Fire-resistant phosphorus containing polyimides and copolyimides

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – From carboxylic acid or derivative thereof

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528168, 528229, 528353, C08G 7310

Patent

active

045365652

ABSTRACT:
Phosphorus-containing polyimides and copolyimides are synthesized in a two-step polycondensation reaction from 1-[(diorganooxyphosphonyl)methyl]-2,4- and -2,6-diaminobenzenes and tetracarboxylic anhydride. The diorgano position of the diorganooxyphosphonyl group includes alkyl, such as ethyl, substituted alkyl, such as 2-chloroethyl, and aryl such as phenyl. The tetracarboxylic anhydrides include compounds such as pyromellitic dianhydride and benzophenone tetracarboxylic dianhydride. The glass transition temperature (Tg) of the polyimides is reduced by incorporation of the (dialkoxyphosphonyl)methyl groups. Both the molecular weight and the thermal stability of the polymers are reduced with increasing concentration of the phosphorus moieties. The phosphorus-containing copolyimides show a considerably higher degree of fire-resistance as compared to that of the corresponding common polyimides, and can be used in matrix composites in very thermally stable high temperature graphite composites for aircraft applications.

REFERENCES:
patent: 3531437 (1970-09-01), Rio
patent: 4082768 (1978-04-01), Renner et al.
patent: 4175174 (1979-11-01), Hermans

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