Coating processes – With post-treatment of coating or coating material – Heating or drying
Reexamination Certificate
1998-04-24
2001-05-22
Cameron, Erma (Department: 1762)
Coating processes
With post-treatment of coating or coating material
Heating or drying
C106S018140, C106S018260, C106S018310
Reexamination Certificate
active
06235347
ABSTRACT:
This invention relates to a process for fire resistant cellulosic materials and rendering cellulosic materials leach resistant. More particularly, the invention relates to a process of using aluminum phosphate to make wood fire resistant and render such wood leach resistant. This invention relates also to a composition comprising cellulosic materials and aluminum phosphate which is fire resistant.
BACKGROUND OF THE INVENTION
Wood, a natural cellulose material, is used in home construction in roofing, frames, support and plywood; however, wood has use restrictions in roofing as there is no approved commercial fire resistant treatment. If homes were not protected with nonflammable roofs, a fire could easily jump from house roof to house roof, especially with high winds.
Effective fire resistant treatment of wood for both exterior and interior uses under conditions of leaching and weathering is needed because desirable properties of wood must be preserved after initial fire resistant treatment.
Fire retardants are added or applied to a cellulosic materials such as wood products to increase the resistance of that cellulosic material to fire. Such materials are less flammable than the cellulosic (wood) they protect. Some fire retardants prevent the spread of flame; others bun and thereby create a layer of char that inhibits further combustion. At the same time, some organic fire retardants may produce fairly toxic gases during exposure of the treated material to fire temperatures which may present problems for persons caught inside a burning building and for fire fighters.
The chemicals in a fire resistant composition determine how it works. Most flame retardants contain elements from any of three groups in the Periodic Table of Elements (Group IIIa (including boron and aluminum), Group Va (including nitrogen, phosphorus, arsenic, and antimony), and Group VIIa (including fluorine, chlorine, and bromine). Aluminum (sometimes as aluminum oxide) increase the amount of char formed in the early stages of a fire. This char forms a protective layer that prevents oxygen from reaching the inner layers of the protected material and thus sustaining the fire.
Phosphorus is a flame retardant in its solid and liquid phases which works by forming a surface layer of protective char on wood. Compounds of phosphoric acid are most frequently used as flame retardants for the first class of materials. On heating, sometimes phosphoric acid reacts with the cellulose to produce large amounts of carbon char and incombustible gases, such as steam and carbon dioxide, which either prevent fire from starting or smother it.
Various U.S. Patents disclose concepts for reportedly rendering wood flame proof. These patents include U.S. Pat. No. 4,981,518 issued to Melvin H. Sachs on Jan. 1, 1991 which discloses a cellulose filler material, such as wood chips, which are rendered nonflammable by encapsulation within a binder which is formed in an exothermic reaction from mixing a powdered base metal oxide and a weak acid, such as aluminum phosphate, which may be in the form of an acidic solution. This patent further discloses a method of making the bonded composite structure including the steps of mixing the weak acid and powdered base metal oxide, encapsulating the fibrous cellulose material within the binder and rendering the fibrous cellulose material nonflammable, thereby forming the slurry mixture into a predetermined form and setting the formed mixture into a solid.
U.S. Pat. No. 4,857,365 which issued to Shozo Hirao et al. on Aug. 15, 1989 and U.S. Pat. No. 4,731,265 which issued to Shozo Hirao et al. on Mar. 15, 1988 disclose a modified wood which is reportedly produced by reacting two water-soluble solutions, one with cations (selected from a group containing aluminum) and one with anions (from a group containing phosphoric acid) which react to form an insoluble, nonflammable, inorganic compound. A method of manufacturing a modified wood material is disclosed in these patents which reportedly can position within a raw wood material, an insoluble, nonflammable, inorganic compound using a highly efficient reaction achieved between cations and anions by sequentially immersing the raw wood material at least three times alternately in each of, and different one from that employed immediately before of a first water-soluble, inorganic substance solution containing cations and a second water-soluble, inorganic substance solution containing anions.
JP 63159008 discloses modified wood which is impregnated with insoluble, incombustible material using two aqueous solutions. A physical stimulus, which may be microwave heating, is given to the wood to promote formation of the insoluble material. Ions with a (3+) charge may be in one solution and phosphate ions in the other.
JP 48046195 discloses that pulp and wood are fireproofed with aluminum phosphate and silicates.
Aluminum phosphate has been manufactured in the United States since the late 1940s. While there is prior art as to compositions for fireproofing wood, including some compositions containing aluminum and some compositions containing phosphorus, a more efficient process and composition for fire resistant wood and rendering it leach resistant is provided herein using aluminum phosphate.
OBJECTS OF THE INVENTION
It an object of the invention to provide a treated cellulosic material which has improved fire-resistant and leach-resistant properties.
It is a further object of the invention to provide a process for preparing a wood shingle and plywood compositions having improved fire-resistant and leach-resistant properties.
It is another object of this invention to provide an aluminum iron phosphate composition which renders wood fire resistant and leach resistant.
The above and other objects are achieved in this invention more particularly described in the specification hereinafter following.
REFERENCES:
patent: 3772060 (1973-11-01), Birchall et al.
patent: 3785845 (1974-01-01), Birchall et al.
patent: 3793105 (1974-02-01), Birchall et al.
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patent: 4731265 (1988-03-01), Hirao et al.
patent: 4734136 (1988-03-01), Burrow
patent: 4857365 (1989-08-01), Hirao et al.
patent: 4981518 (1991-01-01), Sachs
patent: 5096539 (1992-03-01), Allan
patent: 5151225 (1992-09-01), Herndon et al.
patent: 5503920 (1996-04-01), Alkire et al.
patent: 2118013 (1971-12-01), None
patent: 1519772 (1978-08-01), None
patent: 48-046195 (1973-07-01), None
patent: 950741 (1982-08-01), None
patent: 1201268 (1985-12-01), None
Qin et al, Fire Mater. (1993), 17(4), pp. 201-203.*
Translation of SU 1201268, Dec. 1985.*
Full text of Qin et al, Fire Mater. 17(4), pp. 201-203, 1993.*
“The Study and Application of LL Flame Retardant”, Qin Wenquing and Li Feng, Fire and Materials, vol. 17, 201-203 (1993).
The Journal of Inorganic Phosphorus Chemistry, Phosphorus Research Bulletin, 1996, vol. 6, pp. 1-4 Authors: E.J, Griffith, Toan Ngo and Rosa P. Arshinova.
Derwent Abstract: “Silicate-based insulating moulded body prodn.—by reaction bonding foamed alkali silicate particles with mono aluminum phosphate”; EP 634377; Date: 1995.
Derwent Abstract: “Wood fibreboard having flame resistance—has inorganic cpd., phosphate and borate filled in or stuck to cell holes and/or inner walls of cell holes of wood fibre, etc.”; JP 6055507; Date: Mar. 1, 1994.
Derwent Abstract: “Fireproof wooden door—comprises skeleton material comprising parallel laminated wood obtd. By lmainating flameproof treated boards so fibre direction of boards are parallel and surface board”; JP 4136390; Date: May 11, 1992.
Derwent Abstract: “Fireproof wooden door used in complex houses and tall buildings—obtd. By providing lumber surface board on lumber core prepd. By impregnating raw material in treating soln. contg. pref. borate
Arshinova Rose P.
Griffith Edward J.
Griffith Joseph E.
Astaris LLC
Cameron Erma
Griffith Joseph E.
Kirk Ahaji
Thompson & Coburn LLP
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