Fine-particled amphoteric aqueous polymer dispersion method...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymerizing in two or more physically distinct zones

Reexamination Certificate

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C526S328000, C526S329300

Reexamination Certificate

active

07579414

ABSTRACT:
Finely divided, amphoteric, aqueous polymer dispersions which are obtainable by a two-stage polymerization, a prepolymer being prepared in the first polymerization stage from a monomer mixture comprising(a) from 15 to 40% by weight of at least one (meth)acrylate and/or (meth)acrylamide having in each case a free amino group, protonated amino group and/or quaternized amino group,(b) from 40 to 70% by weight of at least one optionally substituted styrene,(c) from 0 to 25% by weight of acrylonitrile and/or methacrylonitrile,(d) from 0.5 to 5% by weight of at least one ethylenically unsaturated monomer comprising acid groups and(e) from 0 to 30% by weight of at least one nonionic, ethylenically unsaturated monomer differing from (b) and (c),the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight,in a solution polymerization in a solvent partly to completely miscible with water, water then being added to the solution/dispersion of the prepolymer and then at least one nonionic, ethylenically unsaturated monomer being subjected to an emulsion polymerization in the aqueous solution of the prepolymer in a second polymerization stage, processes for the preparation of the polymer dispersions by two-stage polymerization and use of the polymer dispersions as sizes for paper, board and cardboard.

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Polymer Latices: Science and Technology, 2ndedition, D.C. Blackley (Springer 1997).

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