Fine grained sintered cemented carbide, process for...

Specialized metallurgical processes – compositions for use therei – Compositions – Consolidated metal powder compositions

Reexamination Certificate

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C075S239000, C075S240000, C075S241000, C075S242000, C428S545000, C051S307000

Reexamination Certificate

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10759478

ABSTRACT:
The invention proposes a fine grained sintered cemented carbide containing chromium and based on WC and a binder based on Co or CoNiFe, and having at least one additional phase comprising at least one carbide or mixed carbide of tantalum. For improving the high-temperature properties while simultaneously maintaining a good trade-off between hardness and bending strength, it is proposed that the sintered cemented carbide contains approximately 0.3 to 4% Ta, as related to the total mass of the sintered cemented carbide, that the WC has a grain size of between 0.1 and 1.3 μm, that the binder phase contains the metals W, Cr and Ta, dissolved in solid solution, and that the at least one additional phase comprises a TaC phase visible by optical microscopy. The invention further relates to a powder-metallurgical process for manufacturing the sintered cemented carbide and to the use of the sintered cemented carbide for manufacturing cutting tools having improved high-temperature properties.

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patent: 40 00 223 (1993-07-01), None
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Egami et al., “Ultra Submicron Hardmetals for Miniature Drills”, Plansee Seminar 89', vol. 2, pp. 53-70 12th Int'l Plansee Seminar.
Egami et al., “Morphology of Vanadium Carbide in Submicron Hardmetals”, 13th Intl' Plansee Seminar, vol. 3 pp. 639-648 (1993).
G. Gille,et al., “A new 0.4 UM WC powder as well as powder-related properties and sintering behavior of of 0.6 to 30 um WC—Co hardmetals”, Proceedings of the 14th Int'l Plansee Seminar AG Reutte (1997) vol. 2 pp. 139-167 HM12.
D. F. Carroll, “Processing and Properties of Ultrafine WC/Co Hard Metals”, Dow Chemical Co., Proceedings of 14th Int'l Plansee Seminar, AG Reutte, (1997) vol. 2 pp. 168-182 HM14.
J. Zackrisson et al., “WC—Co Based Cemented Carbides with Large Cr3C2 Addidtions”, Int'l Journal of Refractory Metal & Hard Metals 16(1998)pp. 417-422.
Opposition by Sandvik AB against De 101 35 790 in German language (Oct. 14, 2005).

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