Chemical apparatus and process disinfecting – deodorizing – preser – Analyzer – structured indicator – or manipulative laboratory... – Calorimeter
Reexamination Certificate
2006-01-12
2009-11-24
Warden, Jill (Department: 1797)
Chemical apparatus and process disinfecting, deodorizing, preser
Analyzer, structured indicator, or manipulative laboratory...
Calorimeter
C422S050000, C422S052000, C422S051000, C422S091000, C428S432000
Reexamination Certificate
active
07622075
ABSTRACT:
A film for detecting fluoride concentrations is disclosed. The film includes an organic matrix having a lipophilic aluminum compound incorporated therein. The lipophilic aluminum compound is adapted to selectively bind with fluoride ions via a binding interaction. The fluoride is detectable through optical or electrochemical detection of the binding interaction.
REFERENCES:
patent: 6472073 (2002-10-01), Singh et al.
patent: 2003/0162960 (2003-08-01), Sessler et al.
patent: 2004/0018631 (2004-01-01), Ward et al.
patent: 2243917 (1991-11-01), None
Antonisse, M. M. G., B. H. M. Snellink-Ruël, A. C. Ion, J. F. J. Engbersen, D. N. Reinhoudt, “Synthesis of Novel Uranyl Salophene Derivatives and Evaluation as Sensing Molecules in Chemically Modified Field Effect Transistors (CHEMFETs),” J Chem. Soc. Perkin Trans. 2, 1999, pp. 1211-1281.
ASTM International; “Standard Test Methods for Fluoride Ion in Water;” D1179-04; ASTM: West Conshohocken, PA, 2005, pp. 1-6.
Bergman, I., “Rapid-response Atmospheric Oxygen Monitor Based on Fluorescence Quenching,” Nature 1968, 218, p. 396.
Harwood, J. E., “The Use of an Ion-Selective Electrode for Routine Fluoride Analyses on Water Samples,” Water Research 1969, 3, pp. 273-280.
Kaizu, Y., N. Misu, K. Tsuji, Y. Kaneko, H. Kobayashi, “Electronic Spectra of the Aluminum(III) Complexes of 5,10,15,-20-Tetraphenylporphin and 2,3,7,8,12,13,17,18-Octaethylporphin,” Bull. Chem. Soc. Jpn. 1985, 58, 103-108.
Lindner, E., K. Tóth, J. Jeney, M. Horváth, E. Pungor, I. Bitter, B. Ágai, L. Töke, “Novel Bis(Crown Ether)-Based Potassium Sensor for Biological Applications,” Mikrochimica Acta 1990, 1, pp. 157-168.
Pioda, L. A. R., V. Stankova, W. Simon, “Highly Selective Potassium Ion Responsive Liquid-Membrane Electrode,” Anal. Lett. 1969, 2, pp. 665-674.
Schulthess, P., D. Ammann, W. Simon, C. Caderas, R. Stepánek, B. Kräeutler, “116. Lipophilic Derivative of Vitamin B12as a Selective Carrier for Anions,” HeIv. Chim. Acta, 1984, 67, pp. 1026-1032.
Yamamoto, H., Shinkai, S., “Molecular Design of Calix[4]arene-Based Sodium-Selective Electrodes Which Show Remarkably High 105.0-105.3Sodium/Potassium Selectivity,” Chem. Lett. 1994, 6, pp. 1115-1118.
Downs, A. J., (Ed.) Chemistry of Aluminum, Gallium, Indium and Thallium, Coordination and Solution of Chemistry, Chapman & Hall: Glasgow, 1993, pp. 432-449.
Kunz, W., J. Henle, W. W. Ninham, “‘Zur Lehre von der Wirkung der Salze’ (about the science of the effect of salts): Franz Hofmeister's historical papers,” Elsevier, Current Opinion in Colloid and Interface Science, 2004, pp. 1-19.
Hulanicki, A., R. Lewandowski, “Some Properties of Ion-Selective Electrodes Based on Poly(Vinyl Chloride) Membranes with Liquid-Ion-Exchanger,” Chem. Anal. Warsaw 1974, 19, 53-61.
Kotrly, S., Sucha, L., Handbook of Chemical Equilibria in Analytical Chemistry, Stability Constants of Complexes with Inorganic Ligands, John Wiley & Sons: New York, 1985, pp. 132-135.
Landis, W. G., J. J. DeFrank, “Enzymatic Hydrolysis of Toxic Organofluorophosphate Compounds,” Methods and Applications in Biodegradation, Biotechnology Series 1990, vol. 4 (Biotechnol. Biodegrad.), pp. 183-201.
Smith, R. M., Martell, A. E., Critical Stability Constants; vol. 4: Inorganic Complexes, Plenum: New York, 1974, pp. 96-103.
International Search Report for S.N. PCT/US2006/07330 dated Aug. 8, 2007 (3 pages).
Adler, A. D., F. R. Longo, J. D. Finarelli, J. Goldmacher, J. Assour, L. Korsakoff, “A Simplified Synthesis formeso-Tetraphenylporphin,” J. Org. Chem. 1967, 32, p. 476.
Aida, T., S. Inoue, “Activation of Carbon Dioxide with Aluminum Porphyrin and Reaction with Epoxide. Studies on (Tetraphenylporphinato)aluminium Alkoxide Having a Long Oxyalkylene Chain as the Alkoxide Group,” J. Am. Chem. Soc. 1983,105, pp. 1304-1309.
Aida T., K. Wada, S. Inoue, “Copolymerization of Epoxides by Aluminium Porphyrin. Reactivity of (Porphinato)aluminum Alkoxide as Growing Species,” Macromolecules 1987, 20, pp. 237-241.
Antonisse, M. M. G., D. N. Reinhoudt, “Potentiometric Anion Selective Sensors,” Electroanalysis 1999, 11, pp. 1035-1048.
Aoba, T., O. Fejerskov, “Dental Fluorosis: Chemistry and Biology,” Crit. Rev. Oral Biol. Med. 2002, 13, pp. 155-170.
Arndt, P., A. Spannenberg, W. Baumann, V. V. Burlakov, U. Rosenthal, S. Becke, T. Weiss, “Reactions of Zicronocene 2-Vinylpyridine Complexes with Diisobutylaluminum Hydride and Fluoride,” Organometallics 2004, 23, pp. 4792-4795.
Aylott, J. W., “Optical Nanosensors—An Enabling Technology for Intracellular Measurements,” Analyst 2003, 128, pp. 309-312.
Badr, I. H. A., M. Diaz, M. F. Hawthorne, L. G. Bachas, “Mercuracarborand “Anti-Crown Ether”-Based Chloride-Sensitive Liquid/Polymeric Membrane Electrodes,” Anal. Chem. 1999, 71, pp. 1371-1377.
Badr, I. H. A., M. E. Meyerhoff, “Fluoride-Selective Optical Sensor Based on Aluminum(III)-Octaethylporphyrin in Thin Polymeric Film: Further Characterization and Practical Application,” Anal. Chem. 2005, 77, pp. 6719-6728.
Badr, I. H. A., M. E. Meyerhoff, “Highly Selective Optical Fluoride Ion Sensor with Submicromolar Detection Limit Based on Aluminum(III) Octaethylporphyrin in Thin Polymeric Film,” J. Am. Chem. Soc. 2005, 127, pp. 5318-5319.
Badr, I. H. A., M. E. Meyerhoff, “Highly Selective Single-Use Fluoride Ion Optical Sensor Based on Aluminium(III)-Salen Complex in Thin Polymeric Film,” Anal. Chim. Acta 2005, 553, pp. 169-176.
Badr, I. H. A., R. D. Johnson, M. Diaz, M. F. Hawthorne, L. G. Bachas, “A Selective Optical Sensor Based on [9]Mercuracarborand-3, a New Type of Ionophore with a Chloride Complexing Cavity,” Anal. Chem. 2000, 72, pp. 4249-4254.
Bakker, E., M. E. Meyerhoff, “Ion-Selective Electrodes for Measurements in Biological Fluids,” Encyclopedia of Electrochemistry 2002, 9, pp. 277-307.
Bakker, E., R. K. Meruva, E. Pretsch, M. E. Meyerhoff, “Selectivity of Polymer Membrane-Based Ion-Selective Electrodes: Self-Consistent Model Describing the Potentiometric Response in Mixed Ion Solutions of Different Charge,” Anal. Chem. 1994, 66, pp. 3021-3030.
Bakker, E., E. Malinowska, R. D. Schiller, M. E. Meyerhoff, “Anion-Selective Membrane Electrodes Based on Metalloporphyrins: The Influence of Lipophilic Anionic and Cationic Sites on Potentiometric Selectivity,” Talanta 1994, 41, pp. 881-890.
Bakker, E., E. Pretsch, P. Bühlmann, “Selectivity of Potentiometric Ion Sensors,” Anal. Chem. 2000, 72, pp. 1127-1133.
Bakker, E., P. Bühlmann, E. Pretsch, “Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 1. General Characteristics,” Chem. Rev. 1997, 97, 3083-3132.
Becker, C., I. Kieltsch, D. Broggini, A. Mezzetti, “Bridging Fluorides and Hard/Soft Mismatch in d6and d8Complexes: The Case of [TI(μ-F)3Ru(PPh3)3],” Inorg. Chem. 2003, 42, pp. 8417-8429.
Bühlmann, P., E. Pretsch, E. Bakker, “Carrier-Based Ion-Selective Electrodes and Bulk Optodes. 2. Ionophores for Potentiometric and Optical Sensors,” Chem. Rev. 1998, 98, pp. 1593-1687.
Chaniotakis, N. A., S. B. Park, M. E. Meyerhoff, “Salicylate-Selective Membrane Electrode Based on Tin(IV) Tetraphenylporphyrin,” Anal. Chem. 1989, 61, pp. 566-570.
Chaniotakis, N. A., A. M. Chasser, M. E. Meyerhoff, J. T. Groves, “Influence of Porphyrin Structure on Anion Selectivities of Manganese(III) Porphyrin Based Membrane Electrodes,” Anal. Chem. 1988, 60, pp. 185-188.
Chen, X., C.-G. Zhan, “Theoretical Determination of Activation Free Energies for Alkaline Hydolysis of Cyclic and Acyclic Phosphodiesters in Aqueous Solution,” J. Phys. Chem. A 2004, 108, 6407-6413.
Dai, S., Q. Ye, E. Wang, M. E. Meyerhoff
Badr Ibrahim H. A.
Meyerhoff Mark E.
Dierker & Associates P.C.
Kwak Dean
The Regents of The University of Michigan
Warden Jill
LandOfFree
Films for detecting fluoride does not yet have a rating. At this time, there are no reviews or comments for this patent.
If you have personal experience with Films for detecting fluoride, we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Films for detecting fluoride will most certainly appreciate the feedback.
Profile ID: LFUS-PAI-O-4052954