Stock material or miscellaneous articles – Composite – Of b – n – p – s – or metal-containing material
Reexamination Certificate
2001-01-31
2003-09-16
Cuneo, Kamand (Department: 2829)
Stock material or miscellaneous articles
Composite
Of b, n, p, s, or metal-containing material
C257S499000, C257S634000, C257S636000, C257S650000, C257S702000, C257S760000, C438S632000, C438S646000, C438S698000, C438S760000, C438S761000, C438S778000, C428S411100, C428S425500, C428S427000, C428S446000
Reexamination Certificate
active
06620534
ABSTRACT:
TECHNICAL FIELD
The present invention relates to the fabrication of integrated circuit devices and, more particularly, to a method of forming a film having enhanced reflow characteristics at low thermal budget.
BACKGROUND
A primary goal in the semiconductor industry is high device yields. Manufacturers often must perform certain process steps on substantially planar wafer surfaces to achieve this end. Where manufacturers attempt to perform these process steps on non-planar surfaces, various problems can occur, resulting in a substantial number of inoperable devices and, therefore, low yield. For example, manufacturers must form metal lines on top of a substantially planar surface to ensure continuity over steps at a reduced thermal budget.
Manufacturers frequently use a layer of oxide, such as borophosphosilicate glass (“BPSG”), to planarize the surface of wafers containing advanced dynamic random access memory (“DRAM”) structures, which have large stacked capacitor heights and high device density. In one process flow, manufacturers deposit a film superjacent to high-profile device structures. The wafer is then heated to reflow the film. Finally, the wafer is made substantially planar by utilizing a conventional technique, such as chemical mechanical planarization (“CMP”).
Reflow is necessary to fill in voids that are created when the film is initially deposited and to smooth the top surface of the film. For reflow to occur, the film must be heated initially to its melting point. Surface tension prevents the film from reflowing even at its melting point. Therefore, the film must be heated even further to overcome the effects of surface tension and, thus, reflow.
However, there are severe limitations on the maximum thermal budget that can be tolerated during the fabrication of state of the art integrated circuit devices. Thermal process steps can cause unwanted diffusion of dopants and destabilization of existing structures. Therefore, manufacturers must carefully restrict the times, temperatures and pressures associated with each thermal process step.
This is particularly true following the source-drain implantation in the manufacture of DRAMs. Reflow of film and activation of source-drain implants are thermal process steps that contribute significantly to the total thermal budget for fabrication of DRAM devices.
For submicron device fabrication, manufacturers are increasingly using rapid thermal processing (“RTP”) steps at high temperatures to achieve shallower junctions and reduced diffusion of dopants. Even where RTP reflow steps at high temperature are employed, it is crucial to utilize films having good reflow properties. RTP steps provide process windows of short duration. Films having good reflow properties permit the manufacturer to use narrow process windows for annealing the film to eliminate the effects of moisture, aging and water absorption, which could otherwise cause void formation and segregation.
For these reasons, manufacturers seek films having enhanced reflow properties at low thermal budgets. The reflow properties of certain films at lower thermal budgets can be enhanced through the introduction of specific dopants, such as boron, phosphorous or germanium, into the material forming the film. However, these doped films often exhibit other undesirable film properties when the concentration of dopants is increased. For example, high concentrations of germanium in BPSG film make the film unstable and moisture-sensitive. Also, the germanium can diffuse into a subjacent active region, thereby unintentionally altering device performance.
SUMMARY OF THE INVENTION
The current invention provides a method of forming a film having enhanced reflow properties at low thermal budget, but not exhibiting the above-mentioned drawbacks.
According to the present invention, a surface layer of material is formed above a base layer of material. The materials are chosen such that the surface layer has a lower melting point than the base layer. In this way, a composite film having two layers is created. After reflow, the surface layer can be removed using a conventional technique, such as CMP.
The advantages of the composite film over conventional films are numerous and include the following: (1) The surface tension of the composite film is lower than that of the base layer, if it were used alone, resulting in enhanced reflow characteristics at low thermal budget; (2) no change is required in the basic composition and chemistry of the constituent materials; (3) the etching characteristics of the base layer are not altered; (4) the surface layer can be formed and subsequently removed using conventional process steps; (5) formation and removal of the surface layer can be easily integrated into a conventional process flow; (6) the base layer remains moisture-resistant; and (7) the base layer acts as a diffusion barrier between underlying active regions and any dopants in the surface layer.
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Sandhu Gurtei
Thakur Randhir P. S.
Cuneo Kamand
Esserman Matthew J.
Kilday Lisa
Micro)n Technology, Inc.
Reed Smith LLP
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