Field emission element and method for manufacturing the same

Electric lamp and discharge devices – Discharge devices having a multipointed or serrated edge...

Reexamination Certificate

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C313S495000

Reexamination Certificate

active

06784604

ABSTRACT:

FIELD OF THE INVENTION
The present invention relates to a field emission element for use in a field emission display (FED) and method for manufacturing the same.
BACKGROUND OF THE INVENTION
Conventional field emission elements and a method for manufacturing same as disclosed in Japanese patent No. 2636630 will now be illustrated with reference to
FIGS. 3A
to
4
E.
FIGS. 3A and 3B
present a top view of field emission elements and an expanded cross-sectional view of a portion X in
FIG. 3A
, respectively.
Referring to
FIG. 3B
, a field emission element includes a glass substrate
10
, on which a cathode conductor
11
, an insulating layer
12
and a gate
13
are disposed. Provided in the insulating layer
12
and the gate
13
is a gate hole
131
, in which a conical emitter
14
is formed on the cathode conductor
11
exposed in the bottom portion of the gate hole
131
. Additionally, a resistance layer may be disposed between the emitter
14
and the cathode conductor
11
.
The gate
13
is made of a metal such as molybdenum (Mo) and niobium (merely abbreviated as Nb), whereas the emitter
14
is made of a metal such as Mo.
The method for manufacturing the field emission element of
FIGS. 3A and 3B
will now be described with reference to
FIGS. 4A
to
4
E.
The cathode conductor
11
, the insulating layer
12
and the gate
13
are laminated on the glass substrate
10
as shown in
FIG. 4A. A
photo-resist layer (not shown) is deposited on the gate
13
and are patterned, and then the gate
13
and the insulating layer
12
are etched, to thereby provide gate holes
131
, as shown in FIG.
4
B. Thereafter, a peeling layer
15
of nickel (Ni) or aluminum (Al) is formed on the surface of the gate
13
by an oblique vapor deposition as shown in
FIG. 4C
, by which neither Ni nor Al is deposited on the bottom portion of the gate hole
131
. Then, the emitter
14
is formed by depositing a material for the emitter
14
, i.e., Mo, on the surface of the peeling layer
15
and also toward the gate hole
131
at a right angle with respect to the glass substrate
10
as shown in FIG.
4
D. Through such vertical vapor deposition, a Mo layer
16
is formed on the peeling layer
15
and the conical emitter
14
is formed within the gate hole
131
. The formation of the conical emitter
14
, which conically fills the gate hole
131
, is a result of a gradual decrease of hole diameter during the growth of the Mo layer
16
above the gate hole
131
. Thereafter, the peeling layer
15
and the Mo layer
16
are removed to complete formation of the field emission element as shown in FIG.
4
E.
In a field emission display, by applying a voltage equal to or less than an anode voltage to the gate
13
, emission of the electrons from the emitter
14
can be controlled. Therefore, the voltage applied to the gate
13
must be reduced in order to reduce the level of the driving voltage of the field emission display. To accomplish this, the distance d
1
(shown in
FIG. 3B
) between the gate
13
and the tip of the emitter
14
needs to be small, which can be achieved by reducing the diameter of the gate hole
131
. The diameter of the gate hole
131
is determined when the gate hole
131
is formed by an etching process shown in FIG.
4
B.
In the process shown in
FIG. 4B
, a photomask aligner, an electron beam exposure apparatus or an ion beam exposure apparatus can be used to form the gate hole
131
. The photomask aligner can be advantageous in reducing time in a patterning process by patterning a large area, e.g., 50 mm×50 mm, at a time, but this device is less suitable in forming a gate hole having a diameter equal to or less than 1 &mgr;m. On the other hand, the electron beam exposure apparatus and the ion beam exposure apparatus are more suitable in forming gate holes having a diameter less than 1 &mgr;m, but offer a limited patterning area, e.g., 1 mm×1 mm, at a time, thereby requiring greater processing time.
The correlation between the diameter d
2
of the gate hole
131
and the height h
1
of the corresponding emitter
14
will now be illustrated. When the diameter d
2
of the gate hole
131
is reduced, the height h
1
of the emitter
14
is also reduced. As evident from the process shown in
FIG. 4D
, the emitter
14
grows until the gate hole
13
is clogged or covered, and such growth depends on the diameter d
2
of the gate hole
131
. Additionally, the aspect ratio (the ratio of the height h
1
to the diameter of the bottom of the emitter
14
) depends on selection of the material of the emitter
14
and conditions for forming the layer. Consequently, a smaller diameter d
2
of the gate hole
131
with other conditions fixed, yields a smaller height of the emitter
14
.
With reference to
FIG. 3B
, if the diameter d
2
of the gate hole
131
is reduced, while holding the height h
2
of the insulating layer
12
fixed, the height h
1
of the emitter
14
is also reduced. Consequently, the tip of the emitter
14
is displaced farther from the gate
13
, lengthening the distance d
1
between the gate
13
and the emitter
14
. Therefore, in order to reduce the level of voltage applied to the gate
13
, the tip of the emitter
14
needs to be closer to the gate
13
by reducing the height h
2
, i.e., thickness, of the insulating layer
12
, while reducing the diameter d
2
of the gate hole
131
.
In such a case, when the insulating layer
12
becomes thinner, electrostatic capacity of a capacitor formed by the cathode conductor
11
and the gate
13
becomes greater and reactive power also becomes greater. To reduce the reactive power, an insulation material of smaller dielectric constant can be chosen for the insulating layer
12
, but the smaller dielectric constant in general induces low breakdown voltage.
Referring to
FIG. 5
, there are plotted dielectric constants and the breakdown voltages of silicon based insulating materials formed into layers by the CVD process. In general, an insulating material of a lower dielectric constant has a lower breakdown voltage than that of a higher dielectric constant as shown in FIG.
5
. Therefore, the reactive power may be reduced by employing the insulating layer
12
made of insulating material with a lower dielectric constant, however, it suffers from a reduction in the breakdown voltage.
SUMMARY OF THE INVENTION
It is, therefore, an object of the present invention to provide a field emission element having a structure which is capable of lowering a driving voltage by reducing a diameter of a gate hole, reducing a reactive power between a gate and a cathode conductor and raising breakdown voltage, and a method for manufacturing such a field emission element, which is capable of providing the gate hole with a diameter equal to or less than 1 &mgr;m through the use of a photomask aligner.
In accordance with one aspect of the present invention, there is provided a field emission element, including: a substrate made of an insulating material; a cathode conductor disposed on the substrate; an insulating layer structure disposed on the cathode conductor wherein the insulating layer structure includes a first insulating layer formed on the cathode conductor and a second insulating layer formed on the first insulating layer; a gate disposed on the second insulating layer; a gate hole provided through the gate and the insulating layer structure to expose a portion of the cathode conductor therethrough; and an emitter of a conical shape formed on the exposed portion of the cathode conductor in the gate hole, wherein the first insulating layer is covered by the second insulating layer at a side surface of the gate hole and a dielectric constant of the first insulating layer is different from that of the second insulating layer.
In accordance with another aspect of the invention, there is provided a field emission display, including: a field emission element, having: a substrate made of an insulating material; a cathode conductor disposed on the substrate; an insulating layer structure disposed on the cathode conductor wherein the insu

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