Fiber-reactive dyestuffs comprising a 5-formylpyrimidine moiety

Organic compounds -- part of the class 532-570 series – Organic compounds – Azo

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534588, 534597, 534598, 534593, 534594, 534617, 534619, 534620, 534621, 534622, 534623, 534624, 534625, 534626, 534627, 534628, 534629, 534630, 534631, 534632, 534633, 534634, 534635, 534636, 534637, 534638, 534642, 534643, 534641, 534652, 534689, 534722, 534725, 534772, 534793, 534800, 534827, 534832, 534836, 534840, 534841, 534860, 534872, 534878, 534880, 544225, 544294, 544296, 544322, 544328, 544329, 544333, 544334, 544335, 260374, C09B 6204, C09B 6206, C09B 6208, C09B 6210, C09B 6224, C09B 62245, C09B

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active

049181696

ABSTRACT:
Reactive dyes suitable for dyeing and printing cellulosic fiber materials by the cold pad-batch process having the formula ##STR1## wherein Fa is a monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazane, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, napthoquinone, pyrenequinone or perylene-tetracarbimide dye radical, X is halogen, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl, a sulfonic acid or phosphonic acid group or a quaternized ammonium group, r is 1 or 2, R is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, and A is a radical of the formula ##STR2## wherein R' is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl or naphthyl each of which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, sulfo or halogen, or a radical of the formula ##STR3## wherein alk and alk' are each independently of the other C.sub.1 -C.sub.6 alkylene, arylene is phenylene or naphthylene, each of which is unsubstituted or substituted by sulfo, carboxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen, R.sub.1 is hydrogen, hydroxyl, sulfo, sulfato, carboxyl, cyano, halogen, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkanoyloxy, carbamoyl or the group --SO.sub.2 --Z, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, sulfato, carboxyl or cyano, Z is --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y and Y is --Cl, --Br, --F, --OSO.sub.3 H, --SSO.sub.3 H, --OCO--CH.sub.3, --OCO--C.sub.6 H.sub.5, --OPO.sub.3 H.sub.2, --OCO--CCl.sub.3, --OCO--CHCl.sub.2, --OCO--CH.sub.2 Cl, OSO.sub.2 --R.sub.4, wherein R.sub.4 is C.sub.1 - C.sub.4 alkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, or --OSO.sub.2 --N(C.sub.1 -C.sub.4 alkyl).sub.2 ; and R" independently has the meaning of R or is a radical of formula (3) above; or R' and R", together with the N atom, form a radical of the formula ##STR4## wherein alk and Z are as defined above.

REFERENCES:
patent: 4709018 (1987-11-01), Seitz
patent: 4754023 (1988-06-01), Tzikas et al.
Chem. Abstract, vol. 79, 146549p (1973).
Chem. Abstract, vol. 108, 108:75112 (1988).

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