Organic compounds -- part of the class 532-570 series – Organic compounds – Azo
Patent
1988-08-19
1990-04-17
Higel, Floyd D.
Organic compounds -- part of the class 532-570 series
Organic compounds
Azo
534588, 534597, 534598, 534593, 534594, 534617, 534619, 534620, 534621, 534622, 534623, 534624, 534625, 534626, 534627, 534628, 534629, 534630, 534631, 534632, 534633, 534634, 534635, 534636, 534637, 534638, 534642, 534643, 534641, 534652, 534689, 534722, 534725, 534772, 534793, 534800, 534827, 534832, 534836, 534840, 534841, 534860, 534872, 534878, 534880, 544225, 544294, 544296, 544322, 544328, 544329, 544333, 544334, 544335, 260374, C09B 6204, C09B 6206, C09B 6208, C09B 6210, C09B 6224, C09B 62245, C09B
Patent
active
049181696
ABSTRACT:
Reactive dyes suitable for dyeing and printing cellulosic fiber materials by the cold pad-batch process having the formula ##STR1## wherein Fa is a monoazo or polyazo, metal complex azo, anthraquinone, phthalocyanine, formazane, azomethine, dioxazine, phenazine, stilbene, triphenylmethane, xanthene, thioxanthone, nitroaryl, napthoquinone, pyrenequinone or perylene-tetracarbimide dye radical, X is halogen, C.sub.1 -C.sub.4 -alkylsulfonyl, phenylsulfonyl, a sulfonic acid or phosphonic acid group or a quaternized ammonium group, r is 1 or 2, R is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, and A is a radical of the formula ##STR2## wherein R' is hydrogen, C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by halogen, hydroxyl, cyano, carboxyl, sulfo, sulfato, C.sub.1 -C.sub.4 -alkoxycarbonyl, C.sub.1 -C.sub.4 -alkoxy or phenyl, C.sub.5 -C.sub.6 cycloalkyl, phenyl or naphthyl each of which is unsubstituted or substituted by C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, sulfo or halogen, or a radical of the formula ##STR3## wherein alk and alk' are each independently of the other C.sub.1 -C.sub.6 alkylene, arylene is phenylene or naphthylene, each of which is unsubstituted or substituted by sulfo, carboxyl, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy or halogen, R.sub.1 is hydrogen, hydroxyl, sulfo, sulfato, carboxyl, cyano, halogen, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkanoyloxy, carbamoyl or the group --SO.sub.2 --Z, R.sub.2 is hydrogen or C.sub.1 -C.sub.4 alkyl, R.sub.3 is hydrogen or C.sub.1 -C.sub.4 alkyl which is unsubstituted or substituted by hydroxyl, sulfo, sulfato, carboxyl or cyano, Z is --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y and Y is --Cl, --Br, --F, --OSO.sub.3 H, --SSO.sub.3 H, --OCO--CH.sub.3, --OCO--C.sub.6 H.sub.5, --OPO.sub.3 H.sub.2, --OCO--CCl.sub.3, --OCO--CHCl.sub.2, --OCO--CH.sub.2 Cl, OSO.sub.2 --R.sub.4, wherein R.sub.4 is C.sub.1 - C.sub.4 alkyl or phenyl which is unsubstituted or substituted by C.sub.1 -C.sub.4 alkyl, or --OSO.sub.2 --N(C.sub.1 -C.sub.4 alkyl).sub.2 ; and R" independently has the meaning of R or is a radical of formula (3) above; or R' and R", together with the N atom, form a radical of the formula ##STR4## wherein alk and Z are as defined above.
REFERENCES:
patent: 4709018 (1987-11-01), Seitz
patent: 4754023 (1988-06-01), Tzikas et al.
Chem. Abstract, vol. 79, 146549p (1973).
Chem. Abstract, vol. 108, 108:75112 (1988).
Ciba-Geigy Corporation
Dochmann George R.
Higel Floyd D.
McC. Roberts Edward
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