Fiber lubricants derived from polyethoxylated and polyoxyalkylat

Stock material or miscellaneous articles – Coated or structually defined flake – particle – cell – strand,... – Rod – strand – filament or fiber

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Details

252 89, 568613, C07C 4300, C07C 4304, D06M 338, D06M 508, D06M 1510

Patent

active

041996470

ABSTRACT:
Lubricants and processing aids for thermoplastic synthetic fibers, particularly polyester and nylon fibers are disclosed together with processes therefor. Said lubricants comprise compounds having the structural formula: ##STR1## in which R and R.sub.1 are independently selected from straight or branched chain aliphatic radicals having about 7 to about 22 carbon atoms; A is oxyethylene or a heteric mixture of oxyethylene and oxypropylene residues derived from the reaction of ethylene oxide and 1,2-propylene oxide in the respective ratio by weight of about 3:7 to about 9:1; and n has a value to produce a compound having a molecular weight of about 300 to about 3000. Said compounds are the ethoxylated or alkoxylated reaction product of the reaction product of an alpha-olefin epoxide and a fatty alcohol.
Where liquid products are desired which contain the higher numbered carbon chain residues, low viscosity compounds can be obtained by oxyalkylating the intermediate obtained by reacting an alpha-olefin epoxide with a fatty alcohol using an ethylene oxide and 1,2-propylene oxide mixture in the respective ratio as set forth above. By properly balancing the carbon chain length of the R and R.sub.1 groups in the lubricant compounds with the oxyethylene or oxyalkylene ratio, variation between insoluble and soluble products can be obtained.

REFERENCES:
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patent: 2690426 (1954-09-01), Jefferson et al.
patent: 2932670 (1960-04-01), Blake
patent: 3676199 (1972-07-01), Hewitt et al.
patent: 3708364 (1973-01-01), Kalopissis
patent: 3943178 (1976-03-01), Stein et al.
patent: 3963628 (1976-06-01), Park

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