Ferrocenyl-1,2-diphosphines, the production thereof and...

Organic compounds -- part of the class 532-570 series – Organic compounds – Heavy metal containing

Reexamination Certificate

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C556S014000, C556S018000, C560S155000, C560S170000, C560S190000

Reexamination Certificate

active

07375241

ABSTRACT:
The invention relates to compounds of formula (I) provided in the form of racemic compounds, mixtures of diastereomers or essentially pure diastereomers, wherein R1represents a hydrogen atom or C1-C4-alkyl, and at least one secondary phosphine depicts an unsubstituted or substituted cyclic phosphine group, or phosphonium salts thereof having one or two monovalent anions or a divalent anion. The compounds of formula (I) can be obtained by means of a novel method and are valuable ligands for catalytically active metal complexes in asymmetrical synthesis

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patent: 97/05094 (1997-02-01), None
Tania Ireland et al., “Ferrocenylliganden mit zwei Phosphanyl-substituenten in α,ε-Position für die Übergangsmetall-katalysierte asymmetrische Hydrierung funktionalisierter Doppelbindungen”, Angewandte Chem., VCH, Verlagsgesellschaft, Weinheim, DE, vol. 111, No. 21, 1999, pp. 3397-3400, XP002179596, ISSN: 0044-8249.

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