Fe-Mn-Cr-Al cryogenix alloy and method of making

Alloys or metallic compositions – Ferrous – Nine percent or more chromium containing

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420 74, 420583, 148608, 148620, 148542, C22C 3838, C21D 800

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058339191

ABSTRACT:
The present invention provides a Fe--Mn--Cr--Al cryogenic alloy having high ductility, strength, toughness and corrosion-resistance, and a process for preparing the same. The cryogenic structural alloy of the invention is prepared by the steps of: air-induced melting of a metallic alloy composition which consists of Fe 48.6 to 64.7 wt %, Mn 25.0 to 35.0 wt %, Cr 10.0 to 13.0 wt %, Al 0.1 to 2.0 wt %, C 0.1 to 0.4 wt % and Si 0.1 to 1.0 wt %; hot-rolling of the melted alloy at 1,090.degree. to 1,110 .degree. C.; and, solution heat treatment of the hot-rolled alloy at 1,040.degree. to 1,060.degree. C. for 50 to 70 minutes. A cryogenic structural alloy of the invention has corrosion-resistance similar to that of conventional 304 stainless steel, higher strength, elongation and toughness than 304 stainless steel, and much higher elongation, corrosion-resistance and toughness than 9% Ni steel; and, therefore, it can be applied for LNG-related facilities including storage tanks, transporting pipes and valves, and transport ships, etc.

REFERENCES:
patent: 4847046 (1989-07-01), Kim
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Soon H. Hong and Young S. Han, "The Effects of Deformation Twins and Strain-Induced .epsilon.-Martensite on Mechanical Properties of an Fe-32Mn-12Cr-0.4C Cryogenic Alloy", Scripta Metallurgica et Materialia, 32(9):1489-1494(1995).
Young G. Kim et al., "Low Temperature Mechanical Behavior of Microalloyed and Controlled-Rolled Fe-Mn-Al-C-X Alloys", Metallurgical Transactions A, 16A:1689-1693(1985).
Young G. Kim et al., "Effect of Aluminum Content on Low Temperature Tensile Properties in Cryogenic Fe/Mn/Al/Nb/C Steels", Metallurgical Transactions A, 17A:2097-2098(1986).
J. Charles et al., "New Cryogenic Materials: Fe-Mn-Al Alloys", Metal Progress, 71-74(1981).
Glenn T. Haddick et al., "New Nickel-Free Austenitic Stainless for Ambient and Cryogenic Service", Metal Progress, 37-40(1978).
J. P. Bruner and D. A. Sarno, "An Evaluation of Three Steels for Cryogenic Service", Adv. Cryo. Eng., 24:529-539(1976).

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