Fabrication of catalytic electrodes for molten carbonate fuel ce

Catalyst – solid sorbent – or support therefor: product or process – Catalyst or precursor therefor – Making catalytic electrode – process only

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264 56, 264104, 419 2, 419 19, 419 23, 429 45, 429221, 502527, H01M 488, B22F 310

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047804378

ABSTRACT:
A porous layer of catalyst material suitable for use as an electrode in a molten carbonate fuel cell includes elongated pores substantially extending across the layer thickness. The catalyst layer is prepared by depositing particulate catalyst material into polymeric flocking on a substrate surface by a procedure such as tape casting. The loaded substrate is heated in a series of steps with rising temperatures to set the tape, thermally decompose the substrate with flocking and sinter bond the catalyst particles into a porous catalytic layer with elongated pores across its thickness. Employed as an electrode, the elongated pores provide distribution of reactant gas into contact with catalyst particles wetted by molten electrolyte.

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