Fabrication of carbon nanotube reinforced epoxy polymer...

Stock material or miscellaneous articles – Web or sheet containing structurally defined element or... – Noninterengaged fiber-containing paper-free web or sheet...

Reexamination Certificate

Rate now

  [ 0.00 ] – not rated yet Voters 0   Comments 0

Details

C523S440000, C523S468000, C977S742000, C977S745000, C977S746000, C977S748000, C977S750000, C977S752000, C977S753000, C977S778000

Reexamination Certificate

active

07601421

ABSTRACT:
The present invention is directed to methods of integrating carbon nanotubes into epoxy polymer composites via chemical functionalization of carbon nanotubes, and to the carbon nanotube-epoxy polymer composites produced by such methods. Integration is enhanced through improved dispersion and/or covalent bonding with the epoxy matrix during the curing process. In general, such methods involve the attachment of chemical moieties (i.e., functional groups) to the sidewall and/or end-cap of carbon nanotubes such that the chemical moieties react with either the epoxy precursor(s) or the curing agent(s) (or both) during the curing process. Additionally, in some embodiments, these or additional chemical moieties can function to facilitate dispersion of the carbon nanotubes by decreasing the van der Waals attractive forces between the nanotubes.

REFERENCES:
patent: 5374415 (1994-12-01), Alig et al.
patent: 6368569 (2002-04-01), Haddon et al.
patent: 6426134 (2002-07-01), Lavin et al.
patent: 6645455 (2003-11-01), Margrave et al.
patent: 2003/0211028 (2003-11-01), Smalley et al.
patent: 2004/0223900 (2004-11-01), Khabashesku et al.
patent: 2006/0047052 (2006-03-01), Barrera et al.
patent: 2006/0155043 (2006-07-01), Johnson et al.
patent: 2007/0259994 (2007-11-01), Tour et al.
patent: 2008/0048364 (2008-02-01), Armeniades et al.
patent: WO 02/060812 (2002-08-01), None
patent: WO 03/080513 (2003-10-01), None
patent: WO 2005/012171 (2005-02-01), None
Iijima, “Helical microtubules of graphitic carbon,” 354 Nature (1991), pp. 56-58.
Iijima et al., “Single-shell carbon nanotubes of 1-nm diameter,” 363 Nature, (1993), pp. 603-605.
Baughman et al., “Carbon Nanotubes-the Route Toward Applications,” 297 Science (2002), pp. 787-792.
Berber et al., “Unusually High Thermal Conductivity of Carbon nanotubes”, 84(20) Phys. Rev. Lett. (2000), pp. 4613-4616.
Lourie et al., “Evaluation of Young's modulus of carbon nanotubes by micro-Raman spectroscopy”, 13 J. Mat. Res. (1998), pp. 2418-2422.
Walters et al., “Elastic strain of freely suspended single-wall carbon nanotube ropes,” 74 Appl. Phys. Lett. (1999), pp. 3803-3805.
Andrews, R., et al., “Nanotube composite carbon fibers,” 75 Appl. Phys. Lett. (1999), pp. 1329-1331.
Barrera, “Key Methods for Developing Single-Wall Nanotube Composites,” 52 Jom (2000), pp. 38-42.
Ausman et al., “Organic Solvent Dispersions of Single-Walled Carbon Nanotubes: Toward Solutions of Pristine Nanotubes”, 104 J. Phys. Chem. B. (2000), pp. 8911-8915.
Bahr et al., “Dissolution of small diameter single-wall carbon nanotubes in organic solvents,” Chem. Commun. (2001), pp. 193-194.
Lourie, et al., “Transmission electron microscopy observations of fracture of single-wall carbon nanotubes . . . ”, 73 Appl. Phys. Lett. (1998), pp. 3527-3529.
Geng et al., “Fabrication and Propertiesof Composites of Poly(ethylene oxide) . . . ”, 14 Adv. Mater. (2002), pp. 1387-1390.
Schadler et al., “Load transfer carbon nanotube epoxy composites”, 73 (26) Appl. Phys. Lett. (1998), pp. 3842-3844.
Ajayan et al., “Single-Walled Carbon nanotube-Polymer Composites: Strength and Weaknesses”, 12(10) Adv. Mater. (2000), pp. 750-753.
Sandler et al, “Development of a dispersion process for carbon nanotubes in an epoxy matrix and the resulting electrical properties”, 40 Polymer (1999), pp. 5967-5971.
Vaccarini et al., “Rerinforcement of an Epoxy Resin by Single Walled Nanotubes”, 544 AIP Conf. Proc. (2000), pp. 521-525.
Gong et al., “Surfactant-Assisted Processing of Carbon Nanotube/Polymer Composites”, 12 Chem. Mater. (2000), pp. 1049-1052.
Spindler-Ranta et al., “Carbon Nanotube Reinforcement of a Filament Winding Resin”, SAMPE 2002 Symposium & Exhibition (2002).
Biercuk et al., “Carbon nanotube composites for thermal management”, 80 (15) Appl. Phys. Lett. (2002), pp. 2767-2769.
Tiano et al., “Functionalization of Single-Wall nanotubes for Improved Structural Composites”, 32nd SAMPE Conf. (2000).
Calvert, P., “Nanotube composites: A recipe for strength,” 399 Nature (1999), pp. 210-211.
Garg et al., “Effect of chemical functionalization on the mechanical properties of carbon nanotubes”, 295 Chem. Phys. Lett. (1998), pp. 275-278.
Frankland et al., “Molecular Simulation of the Influence of Chemical Cross-Links on the Shear Strength of Carbon nanotube . . . ”, 106 J. Phys. Chem. B. (2002), pp. 3046-3048.
Liu et al., “Fullerene Pipes,” 280 Science (1998), pp. 1253-1256.
Chen et al., “Solution Properties of Single-Walled Carbon Nanotubes,” 282 Science (1998), pp. 95-98.
Bahr et al., “Covalent chemistry of single-wall carbon nanotubes,” 12 J. Mater. Chem. (2002), pp. 1952-1958.
Holzinger et al., “Sidewall Functionalization of Carbon Nanotubes,” 40 Angew. Chem. Int. Ed. (2001), pp. 4002-4005.
Khabashesku et al., “Fluorination of Single-Wall Carbon Nanotubes and Subsequent Derivatization Reactions,” 35 Acc. Chem. Res. (2002), pp. 1087-1095.
Shaffer et al., “Dispersion and Packing of Carbon Nanotubes,” 36(11) Carbon (1998), pp. 1603-1612.
Hamon et al., “Dissolution of Siingle-Walled Carbon Nanotubes,” 11(10) Adv. Mater. (1999), pp. 834-840.
Chen, J., et al., “Dissolution of Full-Length Single-Walled Carbon Nanotubes”, 105 J. Phys. Chem. B (2001), pp. 2525-2528.
Riggs, J. E., et al., “Strong Luminescence of Solubilized Carbon Nanotubes”, 122 J. Am. Chem. Soc. (2000), pp. 5879-5880.
Sun et al., “Soluble Dendron-Functionalized Carbon Nanotubes: Preparation, Characterization, and Properties”, 13 Chem. Mater. (2001), pp. 2864-2869.
Ebbesen, “Carbon Nanotubes”, 24 Annu. Rev. Mater. Sci. (1994), pp. 235-264.
Thess et al., “Crystalline Ropes of Metallic Carbon Nanotubes”, 273 Science (1996), pp. 483-487.
Vander Wal, “Flame synthesis of Fe catalyzed single-walled carbon nanotubes and Ni catalyzed nanofibers . . . ”, 349 Chem. Phys. Lett. (2001), pp. 178-184.
Hafner et al., “Catalytic growth of single-wall carbon nanotubes from metal particles,” 296 Chem. Phys. Lett. (1998), pp. 195-202.
Cheng, et al., “Bulk morphology and diameter distribution of single-walled carbon naotubes synthesized by catalytic decomposition of hydrocarbons”, 289 Chem. Phys. Lett. (1998), pp. 602-610.
Nikolaev et al., “Gas-phase catalytic growth of single-walled carbon nanotubes from carbon monoxide,” 313 Chem. Phys. Lett. (1999), pp. 91-97.
O'Connell et al., “Band Gap Fluorescence from Individual Single-Walled Carbon Nanotubes”, 297 Science (2002), pp. 593-596.
Bachilo et al., “Structure-Assigned Optical Spectra of Single-Walled Carbon Nanotubes”, 298 Science (2002), pp. 2361-2366.
Strano, et al., “Electronic Structure Control of Single-Walled Carbon Nanotuve Functionalization,” 301, Science, (2003), pp. 1519-1522.
Chiang et al., “Purification and Characterization of Single-Wall Carbon Nanotubes”, 105 J. Phys. Chem. B (2001), pp. 1157-1161.
Chiang et al., Purification and Characterization of Single-Wall Carbon Nanotubes (SWNTs) Obtained from the Gas-Phase Decomposition of Co (HiPco Process), 105 J. Phys. Chem. B (2001), pp. 8297-8301.
Gu et al., “Cutting Single-Wall Carbon Nanotubes through Fluorination,” 2 (9) Nano Lett. (2002), pp. 1009-1013.
Zhu, J., et al., “Improving the Dispersion and Integration of Single-Walled Carbon Nanotubes in Epoxy Composites throught Functionalization,” 3(8), Nano Lett., (2003), pp. 1107-1113.
Zhang et al., “Sidewall Functionalization of Single-Walled Carbon nanotubes with Hydroxyl Group-Terminated Moieties”, 16 Chem. Mater. (2004), pp. 2055-2061.
Mickelson et al., “Solvation of Flu

LandOfFree

Say what you really think

Search LandOfFree.com for the USA inventors and patents. Rate them and share your experience with other people.

Rating

Fabrication of carbon nanotube reinforced epoxy polymer... does not yet have a rating. At this time, there are no reviews or comments for this patent.

If you have personal experience with Fabrication of carbon nanotube reinforced epoxy polymer..., we encourage you to share that experience with our LandOfFree.com community. Your opinion is very important and Fabrication of carbon nanotube reinforced epoxy polymer... will most certainly appreciate the feedback.

Rate now

     

Profile ID: LFUS-PAI-O-4111960

  Search
All data on this website is collected from public sources. Our data reflects the most accurate information available at the time of publication.