Cleaning compositions for solid surfaces – auxiliary compositions – Cleaning compositions or processes of preparing – For cleaning a specific substrate or removing a specific...
Reexamination Certificate
2001-08-20
2004-06-15
Del Cotto, Gregory R. (Department: 1751)
Cleaning compositions for solid surfaces, auxiliary compositions
Cleaning compositions or processes of preparing
For cleaning a specific substrate or removing a specific...
C510S327000, C510S328000, C510S330000, C510S499000, C510S500000, C510S501000, C510S476000, C510S315000
Reexamination Certificate
active
06750189
ABSTRACT:
FIELD OF THE INVENTION
The present application relates to fabric care compositions which comprise one or more lysine and/or ornithine based polymers which provide enhanced fabric appearance benefits. The high molecular weight polyamino acids of the present invention which mitigate fabric damage and improve fabric appearance can be combined with other fabric softener actives to provide more complete mitigation of fabric damage.
BACKGROUND OF THE INVENTION
The domestic treatment of fabric is a problem known in the art to the formulator of laundry compositions. Hence, It is well known that alternating cycles of using and laundering fabrics and textiles, such as articles of worn clothing and apparel, will inevitably adversely affect the appearance and integrity of the fabric and textile items so used and laundered. Fabrics and textiles simply wear out over time and with use. Laundering of fabrics and textiles is necessary to remove soils and stains which accumulate therein and thereon during ordinary use. However, the laundering operation itself, over many cycles, can accentuate and contribute to the deterioration of the integrity and the appearance of such fabrics and textiles.
Deterioration of fabric integrity and appearance can manifest itself in several ways. Short fibers are dislodged from woven and knit fabric/textile structures by the mechanical action of laundering. These dislodged fibers may form lint, fuzz or “pills” which are visible on the surface of fabrics and diminish the appearance of newness of the fabric. Such a problem of fabric abrasion is even more acute after multiwash cycles.
There exists a long felt need for compositions which provide fabric with protection against damage done due to fabric abrasion. In addition, there is a long felt need to provide compositions which provide a remedy for fabric abrasion damage.
SUMMARY OF THE INVENTION
The present invention meets the aforementioned needs in that it has been surprisingly discovered that polymers comprising lysine and/or ornithine and other compatible amino acid and carboxylic acid residues are suitable for use in rinse-added fabric care compositions to provide provide fabric appearance benefits inter alia mitigation of fabric damage, prevention of fabric mechanical damage.
A first aspect of the present invention relates to rinse-added fabric enhancement or fabric care compositions comprising:
A) from about 0.1%, preferably from about 1%, more preferably from 2.5% to about 30%, preferably to about 20%, more preferably to about 10% by weight, of a polymeric material selected from the group consisting of:
a) homo-condensates of basic amino acids, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
b) co-condensates of basic amino acids, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
c) co-polymers produced from the reaction of one or more basic amino acids with one or more co-condensable compounds;
d) co-polymers produced from the reaction of one or more homo-condensates from (a) or co-condensates from (b) with one or more co-condensable compounds;
e) crosslinked basic amino acid-containing polymers, said crosslinked polymers comprising:
i) one or more basic amino acids;
ii) co-polymers of (i) and one or more co-condensable compounds;
iii) optionally co-polymers produced from the reaction of one or more homo-condensates from (a) or co-condensates from (b) with one or more co-condensable compounds; and
iv) one or more crosslinking unit;
wherein at least one crosslinking unit is derived from a crosslinker which comprises at least two functional groups;
f) co-condensates formed from the reaction of one or more compounds selected from the group consisting of:
i) basic amino acids;
ii) co-condensable compounds;
iii) crosslinking agents; and
g) mixtures thereof;
B) from about 1% to about 80% by weight, of a fabric softening active; and
C) the balance carriers and adjunct ingredients.
A second aspect of the present invention relates to fabric care compositions comprising:
A) from about 0.1%, preferably from about 1%, more preferably from 2.5% to about 30%, preferably to about 20%, more preferably to about 10% by weight, of a polymeric material selected from the group consisting of:
a) homo-condensates of basic amino acid, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
b) co-condensates of basic amino acids, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
c) co-polymers produced from the reaction of one or more basic amino acids with one or more co-condensable compounds.
d) co-polymers produced from the reaction of one or more homo-condensates from (a) or co-condensates from (b) with one or more co-condensable compounds;
e) crosslinked basic amino acid-containing polymers, said crosslinked polymers comprising:
i) one or more basic amino acids;
ii) co-polymers of (i) and one or more co-condensable compounds;
iii) optionally co-polymers produced from the reaction of one or more homo-condensates from (a) or co-condensates from (b) with one or more co-condensable compounds; and
iv) one or more crosslinking unit;
wherein at least one crosslinking unit is derived from a crosslinker which comprises at least two functional groups;
f) co-condensates formed from the reaction of one or more compounds selected from the group consisting of:
i) basic amino acids;
ii) co-condensable compounds;
iii) crosslinking agents:
g) optionally said homo-condensates from (a), co-condensates from (b), co-polymers from (c) and (d), crosslinked polymers from (e), and co-condensates from (f), are alkoxylated with from an average of 0.1 to about 30 alkyleneoxy units; and
h) mixtures thereof;
B) optionally from about 0.01% by weight, of a fabric anti-abrasion polymer comprising:
i) at least one monomeric unit comprising an amide moiety;
ii) at least one monomeric unit comprising an N-oxide moiety;
iii) and mixtures thereof;
C) optionally from about 1%, preferably from about 10%, more preferably from about 20% to about 80%, preferably to about 60%, more preferably to about 45% by weight, of a fabric softening active;
D) optionally less than about 15% by weight, of a principal solvent, preferably said principal solvent has a ClogP of from about 0.15 to about 1;
E) optionally from about 0.001% to about 90% by weight, of one or more dye fixing agents;
F) optionally from about 0.01% to about 50% by weight, of one or more cellulose reactive dye fixing agents;
G) optionally from about 0.01% to about 15% by weight, of a chlorine scavenger;
H) optionally about 0.005% to about 1% by weight, of one or more crystal growth inhibitors;
I) optionally from about 1% to about 12% by weight, of one or more liquid carriers;
J) optionally from about 0.001% to about 1% by weight, of an enzyme;
K) optionally from about 0.01% to about 8% by weight, of a polyolefin emulsion or suspension;
L) optionally from about 0.01% to about 0.2% by weight, of a stabilizer;
M) from about 0.01% by weight, of one or more linear or cyclic polyamines which provide bleach protection; and
N) the balance carrier and adjunct ingredients.
Another aspect of the present invention relates to rinse-added fabric enhancement or fabric care compositions comprising:
A) from about 0.1%, preferably from about 1%, more preferably from 2.5% to about 30%, preferably to about 20%, more preferably to about 10% by weight, of a polymeric material selected from the group consisting of:
a) homo-condensates of basic amino acid, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
b) co-condensates of basic amino acids, said amino acids selected from the group consisting of lysine, ornithine, arginine, and tryptophan;
c) co-polymers produced from the reaction of one or more basic amino acids with one or more co-condensable compounds;
d) co-polymers produced from the reaction of one or more homo-condensates from (a) or co-condensates from (b) with one or more co-condens
Panandiker Rajan Keshav
Randall Sherri Lynn
Zhang Shulin Larry
Del Cotto Gregory R.
Grunzinger Laura R.
Miller Steven W.
The Procter & Gamble & Company
Zerby Kim W.
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