Extrusion process for preparing improved brominated butyl rubber

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Mixing of two or more solid polymers; mixing of solid...

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5253331, 525355, 525356, 5253591, 5253592, 5253593, C08F 822

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active

045635064

ABSTRACT:
A process for the continuous bromination of butyl rubber polymer by contacting the polymer with a brominating agent in a continuous flow device in which means are provided for disengaging reaction by-products and unreacted halogenating agents from the reaction mixture, by deforming and disrupting the brominated polymer surface and injecting a neutralizing agent into the polymer immediately after reaction thereby neutralizing the polymer, comprising contacting a polymer substantially free of acid scavengers, with the brominating agent at elevated temperatures the bromination reaction being carried out in an acid atmosphere, thereby producing a polymer having a substantial fraction of the bromine in the primary allylic position.

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patent: 3936430 (1976-02-01), Schoen et al.
patent: 4185057 (1980-01-01), Rossiter et al.
patent: 4288575 (1981-09-01), Gardner

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