Extrusion of a thermoplastic polymer bearing acid ionic...

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Ion-exchange polymer or process of preparing

Reexamination Certificate

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C521S028000, C521S033000, C521S037000, C429S492000, C429S493000, C210S500410

Reexamination Certificate

active

07956095

ABSTRACT:
The invention relates to a process for the extrusion of thermoplastic polymers having acid ionic groups.The process consists in preparing a mixture composed of a thermoplastic polymer having acid ionic groups and a plasticizer, in extruding the mixture obtained to form a film, then in washing the film obtained in aqueous medium to remove said plasticizer(s). The plasticizer is chosen from non-volatile compounds which are stable with respect to the ionic groups of the polymer, which are soluble in water or in solvents that are miscible with water, said plasticizers being chosen from the compounds that react with the ionic group of the polymer via formation of a weak bond of the hydrogen bond-type, and the compounds that react with the ionic group of the polymer via formation of a strong bond, of the ionic bond-type.

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P. Genova-Dimitrova, B. Baradie, D. Foscallo, C. Poinsignon and J. Y. Sanchez Ionomeric membranes for proton exchange membrane fuel cell (PEMFC): sulfonated polysulfone associated with phosphatoantimonic acid, Journal of Membrane Science 2001, 185, 59-71.
International Search Report, International Application No. PCT/FR2006/000526, dated Mar. 8, 2006.

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