Extractive distillation of isopropyl alcohol with an ether solve

Fuel and related compositions – Liquid fuels – Aluminum or heavy metal – other than lead – containing

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203 18, 203 25, 203 63, 260643R, 203 71, C10L 102

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active

039559394

ABSTRACT:
A water-free mixture of isopropyl alcohol, diisopropyl alcohol, diisopropyl ether and by-products is made by the catalytic hydration of propylene in the gaseous phase at temperatures of 140.degree.-170.degree.C under pressures of 25-40 atmospheres gauge. A water-to-propylene molar ratio of 0.1 to 0.25:1 is maintained in the hydration reaction. The crude product from the hydration reaction is dehydrated or dewatered in two columns without using a foreign withdrawing agent. Instead, diiosopropyl ether formed in the process itself is utilized as the withdrawing agent which is subsequently added to the water-free mixture together with additionally formed by-products. The water-free mixture formed according to the process can be used directly as an additive to gasoline fuel for motor vehicles.

REFERENCES:
patent: 1488605 (1924-04-01), Lichtenthaeler
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patent: 2384796 (1945-09-01), Carmody et al.
patent: 2391084 (1945-12-01), Carmody
patent: 2787586 (1957-04-01), Catterall
patent: 2830090 (1958-04-01), Teter et al.
patent: 2836545 (1958-05-01), Catterall et al.

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