Extraction of uranium from phosphoric acid using supported extra

Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Radioactive metal

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423 10, 210673, 210679, 210504, C01G 4300

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active

044029179

ABSTRACT:
Uranium is extracted from phosphoric acid with organophosphorus extractants supported or impregnated on polymeric resins, and especially macroreticular resins. Suitable extractants include mono and dialkylphenyl esters of phosphoric acid. Uranium may be stripped from the supported or impregnated resins with hotter or more concentrated phosphoric acid, optionally with oxidation to hexavalent form, or with aqueous fluoride solutions.

REFERENCES:
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patent: 3531463 (1970-09-01), Gustafson
patent: 3663467 (1972-05-01), Albright
patent: 3737513 (1973-06-01), Wiewiorowski
patent: 3835214 (1974-09-01), Hurst
patent: 3960762 (1976-06-01), Kroebel
patent: 4220726 (1980-09-01), Warshawsky
patent: 4293529 (1981-10-01), Reese
patent: 4316877 (1982-02-01), Tunick
Flett, "Resin Impregnates: The Current Position", Chemistry and Industry, Aug. 6, 1977, pp. 641-646.
A. Warshawsky, Institute of Mining & Metallurgy, vol. 83, pp. 101-104 (1974).
F. J. Hurst et al., Chemical Engineering, pp. 56-57, (Jan. 3, 1977).

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