Extraction of metal ions from an aqueous solution

Liquid purification or separation – Processes – Liquid/liquid solvent or colloidal extraction or diffusing...

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2105021, 210684, 210688, B01D 1102, B01D 1104

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active

057387915

ABSTRACT:
A method for the making and use of a porous, preferably dimensionally stable, hydrophobic polymer for the extraction of metal ions from an aqueous solution, with the polymer being in the form of a regenerative granulate or powder having an average particle diameter of from 0.1 to 10 mm and pores of from 0.1 to 50 .mu.m, which is obtained by the dissolving of a polymer, with heating, at a temperature above the upper critical demixing temperature Tc in a complexing agent containing hydrophobic liquid, followed by lowering of the temperature, resulting in a porous polymer filled with the hydrophobic liquid, and the mechanical diminution of the solidified mass is disclosed. Favorable results have been attained using polypropylene as the hydrophobic polymer, bis(2,4,4-trimethylpentyl)thio acid as the complexing agent, and with a mixture of dibenzyl toluene and/or polypropylene glycol ether being part of the hydrophobic liquid.

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patent: 5279745 (1994-01-01), Jeffers et al.

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