Chemistry of inorganic compounds – Treating mixture to obtain metal containing compound – Platinum group metal
Reexamination Certificate
2005-02-23
2009-10-06
Mayes, Melvin C (Department: 1793)
Chemistry of inorganic compounds
Treating mixture to obtain metal containing compound
Platinum group metal
Reexamination Certificate
active
07597863
ABSTRACT:
There is provided a novel extractant for palladium capable of improving an extraction speed in comparison with a case of utilizing a DHS being a conventional extractant, and a method for separation and recovery of palladium utilizing the same. The present invention provides a method for obtaining a palladium-containing aqueous solution by bringing an organic phase containing an extractant of a sulfur-containing diamide compound represented by the following structural formula (1):in which R1and R2each represent a group selected from a chain hydrocarbon group having 1 to 18 carbon atoms which may be branched, an alicyclic hydrocarbon group having 1 to 10 carbon atoms, and an aromatic hydrocarbon group having 1 to 14 carbon atom, and R3represents a group represented by {(CH2)nS(CH2)m}Lin which n, m and L each represent an integer of from 1 to 4; extracting palladium by the organic phase; and conducting a back-extraction of palladium, extracted by the organic phase, with an aqueous solution of hydrochloric acid containing thiourea.
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Narita Hirokazu
Tanaka Mikiya
Cohen Stefanie
Mayes Melvin C
Morgan & Lewis & Bockius, LLP
National Institute of Advanced Industrial Science & Technol
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