Extending zeolite catalyst life for disproportionation by treati

Chemistry of hydrocarbon compounds – Aromatic compound synthesis – By alkyl or aryl transfer between molecules – e.g.,...

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208114, 208135, 502214, C10G 1105, C10G 3500

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044567804

ABSTRACT:
There is disclosed a method for decreasing catalyst coking and extending the usable catalyst life by pre-treatment of the catalyst with steam and/or a phosphorus-containing compound. Catalysts benefiting from such pre-treatment comprise crystalline zeolites characterized by a silica to alumina mole ratio of at least 12 and a constraint index, as herein defined, within the approximate range of 1 to 12.

REFERENCES:
patent: 4011276 (1977-03-01), Chu
patent: 4044065 (1977-08-01), Butter et al.
patent: 4097367 (1978-06-01), Haag et al.
patent: 4098837 (1978-07-01), Chu
patent: 4227992 (1980-10-01), Garwood et al.
patent: 4391739 (1983-07-01), Chu
patent: 4397837 (1983-08-01), Rollman

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