Exposure mask for liquid crystal display device and exposure...

Radiation imagery chemistry: process – composition – or product th – Radiation modifying product or process of making – Radiation mask

Reexamination Certificate

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C430S319000, C430S321000, C430S394000

Reexamination Certificate

active

06743555

ABSTRACT:

This application claims the benefit of the Korean Application No. P2001-87160 filed on Dec. 28, 2001, which is hereby incorporated by reference in its entirety.
BACKGROUND OF THE INVENTION
1. Field of the Invention
The present invention relates to a liquid crystal display device, and more particularly, to an exposure mask for a liquid crystal display panel and an exposure method thereof for reducing a shot count in developing a photoresist for a plurality of liquid crystal display panel areas on a substrate.
2. Discussion of the Related Art
Generally, a liquid crystal display device includes upper and lower glass substrates and a liquid crystal layer injected between the upper and lower glass substrates. The lower glass substrate includes a plurality of gate lines arranged in one direction at a predetermined interval and a plurality of data lines arranged in a direction vertical to the gate lines at a predetermined interval such that the gate lines and data lines define a plurality of pixel areas in a matrix. A plurality of pixel electrodes are formed in the pixel areas, respectively. Further, a plurality of thin film transistors are formed adjacent to an intersection between gate and data lines in the pixel areas, respectively. The thin film transistors respectively apply signals of the data lines to the corresponding pixel electrodes in accordance with signals of the gate lines, respectively.
A black matrix layer is positioned on the upper glass substrate to prevent light transmittance through areas other than pixel areas. A color filter layer for realizing colors is positioned in the pixel areas within the black matrix layer. A common electrode is formed on an entire surface of the substrate, including the color filter layer. The liquid crystal layer is injected between the common electrode of the upper glass substrate and the pixel electrode of the lower glass substrate.
Typically, a liquid crystal display panel is fabricated from a process that includes forming a plurality of panels from a large-sized glass substrate. More particularly, the upper glass substrates for a plurality of panels are formed on one large-sized glass substrate and lower glass substrates for a plurality of panels are formed on another large-sized glass substrate. The large-sized glass substrates are bonded together and then the bonded large-sized glass substrates are cut into individual panels. Prior to bonding the large-sized glass substrates containing multiple upper/lower substrates, each of the substrates is first prepared by processes that include deposition, photolithography using a mask, etching, thermal treatment, and the like.
A photolithography process using a mask starts with depositing a material to be patterned on a substrate, coating a photoresist layer on the deposited material, carrying out exposure of the photoresist layer with light using a mask or a reticle having a pattern. The photoresist layer is developed using a developing solution to develop just the portion of the photoresist layer exposed to light or, in the alternative, the portion of the photoresist layer unexposed to the light. Subsequent to developing the photoresist, the deposited material is etched using the developed photoresist layer as a mask to replicate the pattern from the mask or reticle. Thus, the mask or reticle for exposure of the photoresist to light should be aligned correctly with the substrate having the material deposited thereon to precisely provide the desired pattern.
In the fabrication of liquid crystal display panels, there is a scan type exposure method and a stepper type exposure method. The scan type exposure method includes the steps of forming a mask having pattern for each individual panel arranged on the large-sized glass substrate and having the same size as the large-sized glass substrates, aligning the mask with the large-sized glass substrate, and applying light using the mask by scanning. The stepper type exposure method is used for a situation in which a plurality of identical panels are arranged on a glass substrate, and exposure is performed separately on each of the panels using a mask that corresponds to each of the panels.
The scan and stepper type exposure methods both have advantages and disadvantages. The scan type exposure method uses a mask that is more expensive than a reticle/mask used in the stepper method. Further, the mask of the scan type method yields a lower resolution than the reticle/mask used in the stepper method. Hence, the stepper method is preferred over the scanning method in the fabrication of liquid crystal display panels.
In reference to the related art in
FIGS. 1-4
, exposure of a photoresist using the stepper method will be further explained.
FIG. 1
depicts a plurality of individual liquid crystal display panel areas
1

1
,
1
-
2
,
1
-
3
, . . . ,
6
-
3
,
6
-
4
on a general large-sized glass substrate
1
in the related art. More particularly, there are 6 columns that each have 4 individual liquid crystal display panel areas on a central portion of a glass substrate
1
and alignment keys
2
,
3
,
4
, and
5
formed on corners of the glass substrate
1
, respectively. The alignment keys
2
,
3
,
4
, and
5
are for alignment with a stepper and/or other processing devices.
FIG. 2
illustrates an exposure mask
10
for a stepper according to the related art that is used to expose a single liquid crystal display panel area at a time. The exposure mask
10
shown in
FIG. 2
is formed on optical glass for use in a stepper. An exposure mask for use in a stepper can also be referred to as a reticle.
The exposure mask
10
includes a central exposure area
11
, top exposure area
12
, bottom exposure area
15
, a left exposure area
13
, and a right exposure area
14
. The rectangular central exposure area
11
is for exposing a first pattern on a liquid crystal display panel area of a large-sized glass substrate having a plurality of liquid crystal display panel areas. The rectangular top exposure area
12
of the exposure mask, which is above and separated from the central exposure area
11
, is for exposing a second pattern on a top peripheral portion of the large-sized glass substrate. The rectangular bottom exposure area
15
of the exposure mask, which is below and separated from the central exposure area
11
, is for exposing a third pattern on a bottom peripheral portion of the large-sized glass substrate. As shown in
FIG. 2
, the top and bottom exposure areas
12
and
15
are separated by a distance of 2 millimeters from the central exposure area
11
. The rectangular left exposure area
13
of the exposure mask, which is on the left of and separated from the central exposure area
11
, is for exposing a fourth pattern on a left side peripheral portion of the large-sized glass substrate. The rectangular right exposure area
14
of the exposure mask, which is on the right of and separated from the central exposure area
11
, is for exposing a fifth pattern on a right side peripheral portion of the large-sized glass substrate. The top exposure area
12
, bottom exposure area
15
, left exposure area
13
, and right exposure areas
14
are the areas on which alignment keys or test patterns are formed. There is 2 millimeters between each of the exposure areas used as a blade margin in which individual liquid crystal display panels are cut from one another.
An example of an exposure method to develop a photoresist for a plurality of liquid crystal display panel areas on a substrate using the exposure mask
10
shown in
FIG. 2
will be discussed in reference to FIG.
3
and FIG.
4
. The left exposure area
13
of the exposure mask
10
in
FIG. 2
is used to develop the four peripheral portions on the left side of the large-sized glass substrate
1
with four individual shots, as shown in FIG.
3
. The top exposure area
12
of the exposure mask
10
in
FIG. 2
is used to develop the six peripheral portions on the top side of the large-sized glass substrate
1
with six individual shots, as shown in FIG.
4
. In addition, the other periph

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