Explosive double salts and preparation

Explosive and thermic compositions or charges – Containing inorganic nitrogen-oxygen salt – Ammonium nitrate

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149 92, 564512, C06B 3132

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active

044810482

ABSTRACT:
Applicants have discovered a new composition of matter which is an explosive addition compound of ammonium nitrate (AN) and diethylenetriamine trinitrate (DETN) in a 50:50 molar ratio. The compound is stable over extended periods of time only at temperatures higher than 46.degree. C., decomposing to a fine-grained eutectic mixture (which is also believed to be new) of AN and DETN at temperatures lower than 46.degree. C. The compound of the invention has an x-ray density of 1.61 g/cm.sup.3, explodes to form essentially only gaseous products, has higher detonation properties (i.e., detonation velocity and pressure) than those of any mechanical mixture having the same density and composition as the compound of the invention, is a quite insensitive explosive material, can be cast at temperatures attainable by high pressure steam, and is prepared from inexpensive ingredients. Methods of preparing the compound of the invention and the fine-grained eutectic composition of the invention are given.

REFERENCES:
patent: 1968158 (1934-07-01), Naoum et al.
patent: 3110639 (1963-11-01), Clark et al.
patent: 4110136 (1978-08-01), Hershkowitz et al.
patent: 4300962 (1981-11-01), Stinecipher et al.
patent: 4353758 (1982-10-01), Akst et al.

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