Exopeptidase catalyzed site-specific bonding of supports, labels

Chemistry: molecular biology and microbiology – Micro-organism – tissue cell culture or enzyme using process...

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435 71, 435 792, 435181, 436532, 436544, 530816, C12P 100, G01N 33532, G01N 33547, C12N 1106

Patent

active

052348202

ABSTRACT:
An auxiliary substance such as a label, support, or bioactive agent is attached to a protein at a site that is remote from the active site of the protein by the use of exopeptidase and a nucleophile which is an amino acid, amino acid derivative, amine or alcohol. In one embodiment, the nucleophile is attached to the carboxy terminus of a protein by catalysis with exopeptidase to form an adduct and then the adduct or its combination with a linker arm is bound to the auxiliary substance. In another embodiment, the auxiliary substance or its combination with a linker arm is bound to the nucleophile to form an intermediate substance which is then coupled by catalysis with exopeptidase to the carboxy terminus of a protein.

REFERENCES:
Kauer, et al., The Journal of Biological Chemistry. vol. 261, No. 23, 1986, pp. 10695-10700.

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