Exhaust gas cleaner and method for cleaning same

Chemistry of inorganic compounds – Modifying or removing component of normally gaseous mixture – Mixture is exhaust from internal-combustion engine

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Details

4232137, 4232391, 423247, 4232451, B01D 5392, B01D 5356, B01D 5394

Patent

active

056585420

ABSTRACT:
Nitrogen oxides are efficiently removed from an exhaust gas containing nitrogen oxides and an excess amount of oxygen, by (i) disposing an exhaust gas cleaner in a flow path of the exhaust gas, the exhaust gas cleaner comprising a first catalyst comprising 0.2-15 weight % (on a metal basis) of at least one silver salt selected from the group consisting of silver halides, silver sulfate and silver phosphate supported on a porous inorganic oxide on an inlet side and a second catalyst comprising (a) 0.2-15 weight % (on a metal basis) of at least one silver salt selected from the group consisting of silver halides, silver sulfate and silver phosphate and (b) up to 2 weight % (on a metal basis) of copper or copper oxide supported on a porous inorganic oxide on an outlet side; (ii) introducing at least one reducing agent selected from hydrocarbons and oxygen-containing organic compounds into the exhaust gas on an upstream side of the exhaust gas cleaner; and (iii) bringing the exhaust gas into contact with the exhaust gas cleaner at a temperature of 200.degree.-600.degree. C.

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Development of Catalytic Removal Method of Nitrogen Oxides in Presence of SO.sub.x, The 60th Fall Conference of the Japan Chemical Society, Shundo et al. Thesis 3L420, pp. 136-137, Sep. 1990.
Selective Reduction of Nitrogen Oxide by Hydrocarbons(1): Investigation of Zeolite Catalysts, The 60th Fall Conference of the Japan Chemical Society, Hamada et al. Thesis 3L422, pp. 140-141, Sep. 1990.
Selective Reduction of Nitrogen Oxide by Hydrocarbons(2): Investigation of Oxide Catalysts, The 60th Fall Conference of the Japan Chemical Society, Kintaichi et al. Thesis 3L423, pp. 142-143, Sep. 1990.
Hamada et al, Selective Catalytic Reduction of Nitrogen Oxides with Hydrocarbons, Hamada et al. 67th CATSJ Meeting Abstracts: No. A1, vol. 33, No. 2, pp. 59-60, Mar. 1991.

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