Excimer UV fluorescence detection

Radiant energy – Luminophor irradiation – With ultraviolet source

Reexamination Certificate

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C250S458100, C250S459100

Reexamination Certificate

active

10330414

ABSTRACT:
A UV fluorescence detection system is provided comprising a dielectric barrier-discharge excimer lamp, an applied excitation source for communication with the excimer lamp; a fluorescence chamber having a sample gas containing sulfur dioxide, a light sensitive detector is in operative association with the sample chamber; and a signal analyzing and conditioning device for determining the sulfur dioxide content of the sample. The dielectric barrier-discharge excimer lamp possesses a krypton-chloride excimer fill gas mixture. An excitation interference filter and a fluorescence filter may be used in association with the lamp and chamber. In another embodiment, the present invention is a preferred detection method for detecting a specific species comprising the steps of exciting an excimer gas mixture that generates an emission spectrum possessing an specific wavelength, engaging this wavelength with the specific species intended for measurement, exciting the specific species thus inducing a secondary fluorescence or phosphorescence emission that is characteristic of the excited species and analyzing these emissions from the specific species under investigation. In yet another embodiment, the present invention is a preferred UV fluorescence detection method for detecting a specific species comprising the steps of exciting an excimer gas mixture, generating an emission spectrum having an optimal wavelength that enhances the fluorescence emission of the specific species under investigation, engaging the optimal wavelength with the specific species, generating an excited form of the specific species, inducing an emission from the specific species having a characteristic spectral profile, and analyzing the emission for evaluating the content of species under investigation.

REFERENCES:
patent: 3845309 (1974-10-01), Helm et al.
patent: 3944834 (1976-03-01), Chuan et al.
patent: 4045679 (1977-08-01), Wolfe et al.
patent: 4082459 (1978-04-01), Wolfe
patent: 4259646 (1981-03-01), Sze et al.
patent: 4469946 (1984-09-01), Tanaka et al.
patent: 4837484 (1989-06-01), Eliasson et al.
patent: 4857472 (1989-08-01), Wolfbeis
patent: 5504391 (1996-04-01), Turner et al.
patent: 5510158 (1996-04-01), Hiramoto
patent: 6133694 (2000-10-01), Cekic
patent: 6333507 (2001-12-01), Lai et al.
patent: 6342702 (2002-01-01), Jinbo et al.
patent: 6379024 (2002-04-01), Kogure
patent: 6407383 (2002-06-01), Byatt et al.
patent: 6495972 (2002-12-01), Okamoto et al.
patent: 6525472 (2003-02-01), Okugi
patent: 6734629 (2004-05-01), Arnold
patent: 6828568 (2004-12-01), Suzuki et al.
patent: 2002/0140381 (2002-10-01), Golkowski et al.
patent: 2003/0075687 (2003-04-01), Suzuki et al.
Okobe, H., “Fluorescence and Predissociation of Sulfur Dioxide,” J. Amer. Chem. Soc., 93:25, 7095, (1971).
Okabe, H., Fluorescence & Predissociation of Sulfur Dioxide, Dec. 15, 1971, 7095-7096, 93:25 J. Am. Chem. Soc. Note Previously Submitted.
Okabe, H., Fluorescence Quenching of Sulfur Dioxide by Source Emission Gases, Sep. 1976, 487-1489, V.48, No. 11.
Schwarz, F.P., Okabe, H. & Whittaker, J.K., Fluorescence Detection of Sulfur Dioxide in Air at the Parts per Billion Level, Jul. 1974, 1024-1027, vol. 46, No. 8.
Bradshaw, J.D., Rodgers, M.O., and Davis, D.D., Single photon laser-induced fluorescence detection of NO and SO2 for atmospheric Conditions. . . , Jul. 15, 1982, 2493-2500, V.21, No. 14.
Mattee, H.D., Fluorescence & Phosphorescence of SO2 Vapor, Aug. 15, 1968, J. ChemPhy., vol. 49, No. 4.
Mohn, J. & L. Emmenegger, Determination of Sulfur Doixide by Pulsed UV-Fluorescence, 2001, Swiss Federal Laboritories for Materials Testing & Research.
Murray, J.R. & H.T. Powell, KrCI Laser Oscillation at 222nm, Aug, 15, 1976, Applied Phy. Letters, vol. 29, No. 4.
Uchino, Maeda & Hirono, Applications of Excimer Lasers to Laser-Radar Observations of the Upper Atmosphere, Oct. 1979, IEEE J. Quantum Elec., vol. QE-15, No. 10.
Kogelschatz, U., Fundamentials & Applications of Dielectric-Barrier Discharges, May 24, 2000, ABB Corporate Research Ltd., Baden, Switzerland.
Brashears, Setsers & Yu, Emission Spectra of KrXeCl*, KrXeBr*, KrXel*, ArKrF* & ArKrCl*, Jan. 1, 1981, J. Chem. Phys., vol. 74, No. 1.
Zhang & Boyd, Efficient Excimer ultraviolet sources from a dielectric barrier discharge in rare-gas/halogen mixtures, Apr. 9, 1996, J. Appl. Phys., vol. 80, No.2.
Kogelschatz, Ulrich, Silent discharges for the generation of ultraviolet & Vacuum ultraviolet excimer radiation, 1990, Pure & Appld. Chem., vol. 62, No. 9.

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