Ethynylcyclohexene compounds

Organic compounds -- part of the class 532-570 series – Organic compounds – Silicon containing

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549421, 568591, 568668, 568824, 568825, C07F 718, C07C 3100, C07C 4300, C07D30918

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049527169

ABSTRACT:
A process for the manufacture of compounds of the general formula ##STR1## wherein R.sup.1 signifies hydroxy or an etherified hydroxy group, and of zeaxanthin by converting a compound of the general formula ##STR2## wherein R.sup.1 has the above significance, in an inert organic solvent into the acetylenide and reacting this with methyl vinyl ketone, reducing the alcoholate obtained or the alcohol (obtained after hydrolysis of the alcoholate) of the general formula ##STR3## wherein R.sup.1 has the above significance, and subsequently hydrolyzing to give the compound of formula IV and, if desired, converting the compound of formula IV obtained into zeaxanthin.

REFERENCES:
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patent: 4544770 (1985-10-01), Broger
patent: 4701540 (1987-10-01), Lukac et al.
J. Org. Chem. 45, 917 (1980).
Synthesis 459 (1981).
Food Chemistry 5, 15 (1980).
J. Chem. Soc. (c), 404, 1971.
Chem. Abstr. 94, 83655g.
Islamabad J. Sci. 5, 42 (1978).
Pure and Appl. Chem. 51, 535 (1979).

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