Ethylene dimerization and polymerization

Chemistry of hydrocarbon compounds – Unsaturated compound synthesis – By addition of entire unsaturated molecules – e.g.,...

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526 97, 526124, 526129, 526156, 585522, 585524, C07C 226

Patent

active

050435140

ABSTRACT:
A process for dimerizing ethylene comprising contacting ethylene with an insoluble solid catalyst and a cocatalyst, said catalyst having at least on the surface thereof hydrocarbyl ortho ester groups bonded to vanadium or titanium.

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patent: 4284748 (1981-08-01), Welch
patent: 4434083 (1984-02-01), Van de Leemput et al.
patent: 4435518 (1984-03-01), McDaniel et al.
patent: 4452912 (1984-06-01), Bahadir et al.
patent: 4510299 (1985-04-01), Lynch et al.

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