Ethylene copolymerization using diluent gas

Synthetic resins or natural rubbers -- part of the class 520 ser – Synthetic resins – Polymers from only ethylenic monomers or processes of...

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526901, 526 90, 526 64, 526 68, 526123, 526129, C08F 1002

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active

044698550

ABSTRACT:
Ethylene is copolymerized in the gas phase, for example in a fluidized bed, using a gaseous mixture comprising ethylene, at least one olefine monomer containing at least 4 carbon atoms, an inert gaseous diluent and, optionally, hydrogen at a total absolute pressure of at least one MN/m.sup.2. The comonomer preferably contains 6 or 8 carbon atoms. The partial pressure of the comonomer may be in the range from 1 kN/m.sup.2 up to 550 kN/m.sup.2. The inert gaseous diluent typically has a partial pressure of at least 250 kN/m.sup.2 and forms 20% molar of the gaseous mixture. The inert gaseous diluent may be nitrogen and is preferably ethane.

REFERENCES:
patent: 2936303 (1960-05-01), Goins
patent: 4133944 (1979-01-01), Cooper et al.

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