Ether production

Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing

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C07C 4106

Patent

active

050157825

ABSTRACT:
A process for preparing lower molecular weight unsymmetrical ethers such as methyl t-butyl (MTBE) and t-amyl methyl ether (TAME) from an iso-olefin and methanol, the process comprising a preliminary step of contacting the iso-olefin and methanol with a medium-pore zeolite conversion catalyst in at least one reaction zone under conditions sufficient to convert the iso-olefin and methanol to an unsymmetrical ether and then feeding effluent from the preliminary step to an etherification reaction zone containing a macroreticular polystyrenesulfonic acid resin catalyst.

REFERENCES:
patent: 4714787 (1987-12-01), Bell et al.

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