Organic compounds -- part of the class 532-570 series – Organic compounds – Oxygen containing
Patent
1990-03-19
1991-05-14
Mars, Howard T.
Organic compounds -- part of the class 532-570 series
Organic compounds
Oxygen containing
C07C 4106
Patent
active
050157825
ABSTRACT:
A process for preparing lower molecular weight unsymmetrical ethers such as methyl t-butyl (MTBE) and t-amyl methyl ether (TAME) from an iso-olefin and methanol, the process comprising a preliminary step of contacting the iso-olefin and methanol with a medium-pore zeolite conversion catalyst in at least one reaction zone under conditions sufficient to convert the iso-olefin and methanol to an unsymmetrical ether and then feeding effluent from the preliminary step to an etherification reaction zone containing a macroreticular polystyrenesulfonic acid resin catalyst.
REFERENCES:
patent: 4714787 (1987-12-01), Bell et al.
Harandi Mohsen N.
Owen Hartley
Mars Howard T.
McKillop Alexander J.
Mobil Oil Corporation
Speciale Charles J.
Wise L. G.
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