Ether homologation to esters and alcohols using a heterogeneous

Details Ether homologation to esters and alcohols using a heterogeneous Ether homologation to esters and alcohols using a heterogeneous

1983-06-23

1986-11-25

Garner, Vivian

Organic compounds -- part of the class 532-570 series

Organic compounds

Carboxylic acid esters

2604109R, 568907, C07C 2936, C07C 3108, C07C 6737, C07C 6914

Patent

active

046250506

ABSTRACT:
A process for the conversion of dialkyl ethers to homologous carboxylic acid esters and alcohols which comprises reacting a dialkyl ether having from two to about twenty carbon atoms with hydrogen and carbon monoxide in the presence of a heterogeneous sulfided catalyst comprising nickel, optionally in admixture with a co-catalyst selected from the elements of Group VI-B of the Periodic Table.

REFERENCES:
patent: 2593440 (1952-04-01), Hagemeyer et al.
patent: 4189441 (1980-02-01), Braca et al.
patent: 4304946 (1981-12-01), Isogai et al.
patent: 4431835 (1981-07-01), Gauthier-Lafaye et al.
patent: 4482497 (1984-11-01), Rizkalla

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