Ether free organometallic amide compositions

Compositions – Compositions containing a single chemical reactant or plural... – Organic reactant

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2521823, C09K 300

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049448943

ABSTRACT:
An ether free magnesium bisorganoamide of the formula

REFERENCES:
patent: 3742077 (1973-06-01), Kamienski et al.
patent: 3822219 (1974-07-01), Kamienski et al.
patent: 3847883 (1974-11-01), Kamienski et al.
patent: 4139490 (1979-02-01), Halasa et al.
Ashby et al., J. Org. Chem., vol. 43, No. 8, 1978, p. 1564, Reactions of Magnesium Hydrides.3.Stereoselective Reduction of Cyclic and Bicyclic Ketones by Dialkylaminomagnesium Hydrides.
Houser et al., J. Am. Chem. Soc. 69, 295 (1947), Condensation of Certain Esters by Means of Diethylaminomagnesium Bromide.
Frostick et al., J. Am. Chem. Soc. 71, 1350 (1949), Condensations of Esters by Diisopropylaminomagnesium Bromide and Certain Related Reagents.
Bradley et al., Eur. J. Med. Chem. 115, 375 (1980), Synthetic Studies on Meptazinol.Anion Chemistry in the Synthesis of .alpha.-Aryl Lactams.
Ashby et al., J. Organometal. Chem. 14, (1968) 1-11, Concerning The Purity of magnesium and Beryllium Alkyls and Halides Prepared by Different Methods.
Joh et al., Macromolecules, vol. 3, No. 3, May-Jun. 1970, Stereospecific Polymerization of Methyl Methacrylate by Organomagnesium Catalysts with A Magnesium-Nitrogen Bond.
Kamienski, University Microfilms, Ann Arbor, Mich., Order No. 68-9810, pp. 59-60, Synthesis and Properties of Diorganomagnesium Compounds.
Kamienski et al., J. Org. Chem., vol. 30, p. 3498 (1965), Relationship Between Structure and Solubility of Organic Lithium Compounds.

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