Esters of 4-hydroxy-2,9-dioxatricyclo[4.3.1.0.sup.3,7 ] decanes

Details Esters of 4-hydroxy-2,9-dioxatricyclo[4.3.1.0.sup.3,7 ] decanes Esters of 4-hydroxy-2,9-dioxatricyclo[4.3.1.0.sup.3,7 ] decanes

1975-10-30

1977-04-05

Love, Ethel G.

Chemistry of carbon compounds

Miscellaneous organic carbon compounds

C-metal

424278, C07D31908

Patent

active

040161765

ABSTRACT:
Compounds consisting of esters of 4-hydroxy-2,9-dioxatricyclo[4.3.1.0.sup.3,7 ] decane having the formulae: ##STR1## in which formulae R.sub.1 is an alkyl radical having at most 4 carbon atoms, one of the radicals R.sub.2 and R.sub.3 is hydrogen and, when R.sub.2 is a hydrogen radical, R.sub.3 is a carbamyloxy radical and, when R.sub.3 is a hydrogen radical, R.sub.2 is a carbamyloxy, or an alkanoyl radical having at most 5 carbon atoms, the said carbamyloxy radical having the formula --OCONHR in which R is a hydrogen allyl, phenyl, cyclohexyl or an alkyl radical having at most 4 carbon atoms. The compounds are useful as sedatives and narcotics and can be produced by several different processes.

REFERENCES:
patent: 3185692 (1965-05-01), Judd
patent: 3324000 (1967-06-01), Judd
patent: 3455912 (1969-07-01), Eitel et al.
patent: 3917651 (1975-11-01), Thies
Finar, Fundamental Principles Organic Chemistry, p. 459.
Thies, Tetrahedron Letters, No. 35, pp. 3087-3090 (1970).

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