Esterification of neo acids by the use of cation exchange resins

Chemistry of carbon compounds – Miscellaneous organic carbon compounds – C-metal

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260404, 2604045, 260399, 2604109R, 560254, 560250, 560251, 560252, 560253, 560264, 560265, C09F 508, C08H 300

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active

043327389

ABSTRACT:
The esterification of neo acids catalyzed by the presence of a macro-reticular structured sulfonic acid cation exchange resin proceeds under mild conditions with a wide variety of alcohols to give readily recoverable esters in high yields and high purity and an easily recoverable and reusable catalyst.

REFERENCES:
patent: 2936315 (1960-05-01), Whitaker
patent: 3037052 (1962-05-01), Bortnick
patent: 3349107 (1967-10-01), Pawlenko et al.
patent: 3562300 (1971-02-01), Chao et al.
patent: 3579548 (1971-05-01), Whyte
patent: 3590073 (1971-06-01), Carr et al.
patent: 3694382 (1972-09-01), Kleiman et al.
patent: 4125549 (1978-11-01), Coopersmith
A Paper by Coopersmith et al. entitled "Preparation of Hydrolytic Stability of Trialkylacetic Acid Esters", I&EC, 5, No. 1, pp. 46-79, (Mar. 1966).

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