Ester production method by transesterification reaction...

Organic compounds -- part of the class 532-570 series – Organic compounds – Fatty compounds having an acid moiety which contains the...

Reexamination Certificate

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C560S234000

Reexamination Certificate

active

10544822

ABSTRACT:
It is an object of this invention to provide a method for producing an ester by a transesterification reaction in which the reaction can be stably performed in a short time at a pressure approximately equal to normal pressure. The ester is produced by a transesterification reaction in which a starting material ester and an alcohol are brought into contact with a solid acid catalyst that displays the characteristics of a very strong acid in terms of the absolute value of argon adsorption heat ranging from 15 to 22 kJ/mol. In particular, it is preferable that the starting material ester in a liquid phase and alcohol in a vapor phase be brought into contact with the solid acid catalyst, and that the starting material ester be oil or fat, and the alcohol be methanol or ethanol.

REFERENCES:
patent: 6204424 (2001-03-01), Yadav
patent: 6376701 (2002-04-01), Chavan et al.
patent: 6-313188 (1994-11-01), None
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patent: 9-235573 (1997-09-01), None
patent: 2000-143586 (2000-05-01), None
patent: WO 01/88072 (2001-11-01), None
Transesterification of Sunflower Oil in Situ, Siler-Marinkovic, et al., Fuel, IPC Science and Technology Press, 1998, pp. 1389-1391.
Measurement of Heat of Argon Adsorption for the Evaluation of Relative Acid Strength of Some Sulfated Metal Oxides and H-type Zeolites, Matsuhashi, et al., Journal of Physical Chemistry B, vol. 105, No. 40, pp. 9669-9671 (2001).

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